Organic–inorganic hybrid electrolytes from ionic liquid-functionalized octasilsesquioxane for lithium metal batteries

Yang, Guang; Chanthad, Chalathorn; Oh, Hyukkeun; Ayhan, Ismail Alperen; Wang, Qing

doi:10.1039/c7ta04599a

Cited by 66 publications

(41 citation statements)

References 55 publications

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“…The sol-gel approach is a simple and low-temperature method to produce OIH which allows to control the chemical composition of products. Compounds produced by the sol-gel process have many applications in superhydrophobic surfaces [45], electrolytes [46], biosensors [47], corrosion protection [48], etc.…”

Section: Sol-gel and Solvothermal Methodsmentioning

confidence: 99%

Application of Organic-Inorganic Hybrids in Chemical Analysis, Bio- and Environmental Monitoring

et al. 2020

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Organic-inorganic hybrids (OIH) are considered to be a powerful platform for applications in many research and industrial fields. This review highlights the application of OIH for chemical analysis, biosensors, and environmental monitoring. A methodology toward metrological traceability measurement and standardization of OIH and demonstration of the role of mathematical modeling in biosensor design are also presented. The importance of the development of novel types of OIH for biosensing applications is highlighted. Finally, current trends in nanometrology and nanobiosensors are presented.

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Section: Sol-gel and Solvothermal Methodsmentioning

confidence: 99%

Application of Organic-Inorganic Hybrids in Chemical Analysis, Bio- and Environmental Monitoring

et al. 2020

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“…[14] Thus, developing organic-inorganic CSEs with remarkable performance appearst ob e an attractive research topic and might be an effective strategy for improving the performance of advanced ASSBs. [15] To date, av ariety of organic-inorganic CSEsh aveb een reported. Herein, we summarize the current development of organic-inorganic CSEs, in terms of the ion-transport mechanism,e lectrochemicala nd mechanical properties, and their potentiala nd challenges fora pplication in ASSBs.…”

Section: Introductionmentioning

confidence: 99%

“…Compared with SPEs and ISEs, organic–inorganic CSEs possess outstanding mechanical properties, high ionic conductivity, and good interfacial stability . Thus, developing organic–inorganic CSEs with remarkable performance appears to be an attractive research topic and might be an effective strategy for improving the performance of advanced ASSBs . To date, a variety of organic–inorganic CSEs have been reported.…”

Section: Introductionmentioning

confidence: 99%

Recent Progress in Organic–Inorganic Composite Solid Electrolytes for All‐Solid‐State Lithium Batteries

Zhang

Qin

et al. 2019

Chemistry A European J

123

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Conventional lithium-ion batteries, with flammable organic liquid electrolytes, have seriouss afety problems, which greatly limit their application.A ll-solid-state batteries (ASSBs) have received extensive attention from large-scale energy-storage fields,s uch as electric vehicles (EVs) and intelligent powerg rids, due to their benefits in safety,e nergy density,a nd thermostability.A st he key component of ASSBs, solid electrolytes determine the properties of ASSBs. In past decades, various kinds of solid electrolytes, such as polymers and inorganic electrolytes, have been explored.Amongt hese candidates, organic-inorganic composite solid electrolytes (CSEs) that integrate the advantages of these two differente lectrolytes have been regarded as promising electrolytes for high-performanceA SSBs, and extensive studies have been carried out. Herein,r ecent progress in organic-inorganic CSEs is summarized in terms of the inorganic component, electrochemical performance, effects of the inorganicc eramic nanostructure, and ionic conducting mechanism. Finally,t he main challenges and perspectiveso fo rganic-inorganic CSEs are highlighted for future development.

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“…Functional organic–inorganic hybrid materials are currently under the spotlight of material research. These tailor‐made materials with remarkable chemical and physical properties find applications in capacitors, biomedicine, batteries, solar cells, fuel cells, biosensors, and as heterogeneous catalysts . To be specific, there are recent reports on photocatalyst materials used for wastewater disinfection and decontamination, water splitting and hydrogen production, and targeted cancer cells therapy .…”

Section: Introductionmentioning

confidence: 99%

CuS‐functionalized cellulose based aerogel as biocatalyst for removal of organic dye

Saeed

Bano

Sun

et al. 2018

J of Applied Polymer Sci

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CuS‐functionalized cellulose based aerogel (CBA) with 3D macroporous structure was synthesized by in situ deposition of visible light responsive CuS photocatalyst. Hexagonal CuS was deposited onto the outer and inner walls of CBA matrix. CuS/CBA composite catalyst has hierarchical porous structure and abundance in functional groups supporting CuS on CBA surface that enhance photodecomposition of methylene blue (MB). The CuS/CBA composite was characterized by XRD, FTIR, SEM‐EDS, Atomic Absorption Analysis, and XPS analysis. Photodegradation rate of MB by CuS/CBA composite catalyst in visible light was 94.1%, whereas, 67.4% for pure CuS. Initial MB concentration effects, pH change, and variations in CuS/CBA dosage on overall reaction kinetics were also studied. CuS/CBA composite catalyst carried out Photo‐Fenton like reactions which decomposed 97% MB within 6 min, by producing hydroxyl radicals from chemical and photocatalytic reactions. CuS/CBA composite catalyst was recycled and reused. It retained over 80% MB degradation rate even after five consecutive cycles. CuS/CBA composite can be used as biocatalyst for removal of organic dyes. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 47404.

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Organic–inorganic hybrid electrolytes from ionic liquid-functionalized octasilsesquioxane for lithium metal batteries

Abstract: Ionic liquid-based solid electrolytes with outstanding room-temperature ionic conductivity and excellent electrochemical stability are developed for all-solid-state Li metal batteries.

Cited by 66 publications

References 55 publications

Application of Organic-Inorganic Hybrids in Chemical Analysis, Bio- and Environmental Monitoring

Application of Organic-Inorganic Hybrids in Chemical Analysis, Bio- and Environmental Monitoring

Recent Progress in Organic–Inorganic Composite Solid Electrolytes for All‐Solid‐State Lithium Batteries

CuS‐functionalized cellulose based aerogel as biocatalyst for removal of organic dye

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