Organic-moiety-engineering on copper surface for carbon dioxide reduction

Lu, Chenbao; Su, Yuezeng; Zhu, Jun; Sun, Jun; Zhuang, Xiaodong

doi:10.1039/d3cc01049j

Cited by 6 publications

(1 citation statement)

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“…Thus, the adlayer acts as a protective layer for the catalyst under rigorous conditions, suggesting an efficient strategy for the acidic CO 2 RR. 17,48,49,53,81,82 Adlayers commonly used for the acidic CO 2 RR are ionomers that consist of a hydrophobic backbone, side chains and hydrophilic ionic groups. Hydrated cations migrate through the hydrophilic channel established by the SO 3 − ionic groups of the ionomer, which exhibit a greater affinity for K + than for protons.…”

Section: Strategies For the Acidic Co2rr: Electrocatalysts Electrodes...mentioning

confidence: 99%

Acidic CO₂ electroreduction for high CO₂ utilization: catalysts, electrodes, and electrolyzers

Lee,

et al. 2024

Nanoscale

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Section: Strategies For the Acidic Co2rr: Electrocatalysts Electrodes...mentioning

confidence: 99%

Acidic CO₂ electroreduction for high CO₂ utilization: catalysts, electrodes, and electrolyzers

Lee,

et al. 2024

Nanoscale

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Regulating Organic Modifiers on Metal‐Based Catalysts for Enhanced Electrocatalytic CO₂ Reduction

Li,

Zheng,

Zhu

et al. 2024

Chemistry An Asian Journal

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Electrochemical CO2 reduction reaction (CO2RR) has been proved as a promising pathway for valuable chemical production and sustainable carbon cycling. Various regulatory strategies have been explored to boost CO2RR performance. Among these, metal‐based electrocatalytic CO2RR systems regulated by organic modifiers have been shown to play a pivotal role in regulating the complex catalytic processes. Herein, we provide an overview of the recent effective research for regulating the organic modifiers on metal‐based catalyst to enhance CO2RR performance. Two main fundamental mechanisms of enhanced CO2RR with organic modifiers are discussed, including controlling the local microenvironment (local concentration of reactant/intermediate, local pH, local electric field) at the electrode surface and modulating intrinsic catalytic active sites (crystal and electronic structure). Moreover, effective strategies to preserve a stable organic modifier/catalysts interface are also reviewed. Finally, the challenges and prospects faced by organic modifiers regulated metal‐based catalyst in CO2RR are proposed. We hope this review will provide a systematic and comprehensive understanding of the actual impacts of organic modifiers on the development of efficient CO2RR catalysts with favorable activity, selectivity, and stability.

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Achieving green synthesis of high-value-added chemicals via N-integrated CO2 co-reduction: a review

Wang,

Liu,

et al. 2024

Rare Met.

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Organic-moiety-engineering on copper surface for carbon dioxide reduction

Abstract: Electrochemical conversion of carbon dioxide (CO2) into value-added products powered by sustainable electricity is considered as one of the most promising strategies for carbon neutrality. Among the products, hydrocarbons, especially...

Cited by 6 publications

References 99 publications

Acidic CO₂ electroreduction for high CO₂ utilization: catalysts, electrodes, and electrolyzers

Acidic CO₂ electroreduction for high CO₂ utilization: catalysts, electrodes, and electrolyzers

Regulating Organic Modifiers on Metal‐Based Catalysts for Enhanced Electrocatalytic CO₂ Reduction

Achieving green synthesis of high-value-added chemicals via N-integrated CO2 co-reduction: a review

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Organic-moiety-engineering on copper surface for carbon dioxide reduction

Abstract: Electrochemical conversion of carbon dioxide (CO2) into value-added products powered by sustainable electricity is considered as one of the most promising strategies for carbon neutrality. Among the products, hydrocarbons, especially...

Cited by 6 publications

References 99 publications

Acidic CO2 electroreduction for high CO2 utilization: catalysts, electrodes, and electrolyzers

Acidic CO2 electroreduction for high CO2 utilization: catalysts, electrodes, and electrolyzers

Regulating Organic Modifiers on Metal‐Based Catalysts for Enhanced Electrocatalytic CO2 Reduction

Achieving green synthesis of high-value-added chemicals via N-integrated CO2 co-reduction: a review

Contact Info

Product

Resources

About

Acidic CO₂ electroreduction for high CO₂ utilization: catalysts, electrodes, and electrolyzers

Acidic CO₂ electroreduction for high CO₂ utilization: catalysts, electrodes, and electrolyzers

Regulating Organic Modifiers on Metal‐Based Catalysts for Enhanced Electrocatalytic CO₂ Reduction