Organic reactions of selection Π-complexes annual survey covering the year 1984

Rockett, B. W.; Marr, G.

doi:10.1016/0022-328x(86)80166-8

Cited by 11 publications

(1 citation statement)

References 258 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…A new work on iron porphyrins, ferrocenes and related iron compounds has been summarized; among the topics discussed are organic reactions of selected π-complexes [ 545 ], stereochemistry of metallocenes [ 546 ] and the recent chemistry of ferrocene compounds [ 547 , 548 ]. Other topics of recent interest are: bridged ferrocenes [ 549 ], reaction of the isodicyclopentadiene anion with Fe(II)(acac) 2 (Py) 2 (to yield ferrocene derivatives) [ 550 ], preparation of iron-polyarene sandwich compounds [ 551 ], and crystal structure of [ 2 ]metacyclo[ 2 ](1,1′) ferrocenophane [ 552 ].…”

Section: Miscellaneous Recent Resultsmentioning

confidence: 99%

New chemical and stereochemical applications of organoiron complexes

Fatiadi

1991

J. RES. NATL. INST. STAN.

View full text Add to dashboard Cite

The objective of this review is to provide a current overview of the rapidly developing chemistry of organometallic complexes and particularly organoiron complexes useful in asymmetric and stereoselective reactions. Also covered are stereoselective reactions of α, β-unsaturated acyl ligands bound to the chiral auxiliary [(η5-C5H5) Fe(CO)(PPh3)] and new applications of organoiron complexes in the synthesis of natural products. The mechanistic aspects and stabilizing effects of the Fe(CO)3 group for alkenes or conjugated dienes are discussed. A brief summary of recent work on the special role of iron in biological reactions is also included.

show abstract