Organometallic Complexes of Pyrazolylborates and Related Ligands

Sadimenko, Alexander P.

doi:10.1016/s0065-2725(01)81012-6

Cited by 19 publications

(6 citation statements)

References 677 publications

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“…More than 200 different Tp [25][26][27]. Their widespread use likely stems from the ease with which they can be usually prepared and how their steric and electronic effects can be altered simply by changing the number and nature of the substituents on the pyrazolyl rings or the boron atom [28][29][30].…”

Section: Scorpionate Ligandsmentioning

confidence: 99%

Synthetic Bioinorganic Chemistry: Scorpionates Turn 50

Rabinovich

2016

Structure and Bonding

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The coordination chemistry of scorpionates, anionic tripodal boroncentered ligands that readily bind to virtually all main group, transition, and f-block metals, has had a profound effect in the development of synthetic bioinorganic chemistry during the past 50 years. Highlighted in this article are some of the most meaningful results published in the area, primarily in the preparation of structural and functional model compounds for the active sites in metalloproteins and metalloenzymes, a theme that encompasses topics as diverse as nitrogen fixation and heavy metal poisoning. It has also been 50 years since the genesis of Structure and Bonding, so let this account also be a celebration of the many contributions that the staunch serial has had on the entire field of inorganic chemistry during the past half century.

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Section: Scorpionate Ligandsmentioning

confidence: 99%

Synthetic Bioinorganic Chemistry: Scorpionates Turn 50

Rabinovich

2016

Structure and Bonding

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“…Carmona et al described the C-H activation and coordination chemistry of rhodium-and iridium-tris(pyrazolyl)borate complexes [36]. A generaI review on organometallic complexes of pyrazolylborates and related ligands spanning from nontransition metals to copper, silver, and gold species has been written by Sadimenko [37].…”

Section: Introductionmentioning

confidence: 99%

Synthesis and Properties of Poly(pyrazolyl)borate and Related Boron-Centered Scorpionate Ligands. Part A: Pyrazole-Based Systems

Santini¹,

Pellei²,

Lobbia³

et al. 2010

MROC

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This review is intended to cover the developments in the chemistry of poly(azolyl)borates through the years 2000-2008, based on the main synthetic methods, coordination properties, spectroscopic and structural features of this important class of ligands. The subject matter is the chemistry of substituted bis-, tris-and tetrakis-(pyrazolyl)borate ligands. In this review we provide essential information to allow the reader to probe more deeply into the main aspects of the chemistry of these fascinating and flexible ligands. This review would also demonstrate the enormous potential of poly(pyrazolyl)borates chemistry, as also the future perspectives in this field.

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“…-N-Complexes 131 are typical for azoles [14,22,79,80]. Bis-azole complexes of the type 132 have not yet been discovered, but a pyrazolcyclopentadienyl ruthenium complex 133 [14,81] and imidazolecarbene compounds 134 [82] were isolated.…”

mentioning

confidence: 99%

Coordination Aspects in Modern Inorganic Chemistry

Garnovskii¹,

Sennikova²,

Kharisov³

2009

TOICJ

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Main types of coordination compounds in modern inorganic chemistry are discussed. Principal synthesis techniques for metal complexes and the problem of competitive coordination of ambident hard-soft ligands are discussed. A considerable attention is paid to polyfunctional materials, obtained on the basis of coordination compounds, especially molecular magnetics, organic light-emitting devices, and chemosensors.

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Organometallic Complexes of Pyrazolylborates and Related Ligands

Cited by 19 publications

References 677 publications

Synthetic Bioinorganic Chemistry: Scorpionates Turn 50

Synthetic Bioinorganic Chemistry: Scorpionates Turn 50

Synthesis and Properties of Poly(pyrazolyl)borate and Related Boron-Centered Scorpionate Ligands. Part A: Pyrazole-Based Systems

Coordination Aspects in Modern Inorganic Chemistry

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