Organometallic Polymers by Ring-Opening Metathesis Polymerization (ROMP) Reactions

Drăguţan, Ileana; Drăguţan, Valerian; Demonceau, Albert

doi:10.1016/b978-0-12-409547-2.14232-5

Reference Module in Chemistry, Molecular Sciences and Chemical Engineering 2018

DOI: 10.1016/b978-0-12-409547-2.14232-5

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Organometallic Polymers by Ring-Opening Metathesis Polymerization (ROMP) Reactions

Ileana Drăguţan¹,

Valerian Drăguţan²,

Albert Demonceau³

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2022

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Palladium-Catalyzed Difunctionalization of Norbornenes via Arylation and Alkynylation

Shi

Liu

2022

J. Org. Chem.

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We report the first general and practical method for the addition of aryl halides and alkynes to norbornenes with palladium catalysis. Norbornenes have been used as the unsaturated acceptors of aryl and alkynyl groups to construct saturated bridged C–C bonds. The combination of Pd(OAc)2/PCy3HBF4 has been identified as the optimal system promoting difunctionalization of norbornenes via the C–X/C–H bond cleavage and highly selective C(sp3)–C(sp2)/C(sp3)–C(sp) bond formation. Broad substrate scope and excellent functional group tolerance have been achieved to show the high efficiency of this approach. Mechanism studies based on experiments and DFT have been performed to gain insights into the catalytic mechanism.

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Palladium-Catalyzed Difunctionalization of Norbornenes via Arylation and Alkynylation

Shi

Liu

2022

J. Org. Chem.

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show abstract

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Organometallic Polymers by Ring-Opening Metathesis Polymerization (ROMP) Reactions

Cited by 1 publication

References 75 publications

Palladium-Catalyzed Difunctionalization of Norbornenes via Arylation and Alkynylation

Palladium-Catalyzed Difunctionalization of Norbornenes via Arylation and Alkynylation

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