Organometallic Polymers with Transition Metals in the Main Chain

Nguyen, Paul; Gómez‐Elipe, Paloma; Manners, Ian

doi:10.1021/cr960113u

Cited by 825 publications

(460 citation statements)

References 258 publications

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“…This two-wave redox response is similar to that observed for oligo-and poly(ferrocenylsilanes) reported by Manners and coworkers [2] and polysiloxanes functionalized with diferrocenylmethylvinylsilanes [33 ]. This electrochemical behaviour is consistent with the existence of appreciable interactions between the two iron centers bridged by a silicon atom.…”

Section: Electrochemical Behaviour Of the Copolymerssupporting

confidence: 88%

“…New materials with interesting properties for various fields such as electrochemistry, materials science, organic synthesis and catalysis have been reported [1,2]. The excellent thermal and photochemical stability as well as the unique and valuable redox properties of ferrocenes are well known, and in recent years a large number of research groups have investigated various polymer systems with ferrocenyl-containing structures.…”

Section: Introductionmentioning

confidence: 99%

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Electrochemical and bioelectrocatalytical properties of novel block-copolymers containing interacting ferrocenyl units

Armada¹,

Losada²,

López-Villanueva

et al. 2008

Journal of Organometallic Chemistry

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The electrochemical characterization of three different polystyrene-b-polybutadiene block-copolymers, functionalized with diferrocenylsilane units, is reported. The PB-blocks have been functionalized with different fractions of electronically communicated, PS m -PB" p (HSiMeFc 2 ) p units, where m = 615, n = 53, p = 39 (1), m = 375, n = 92, p = 76 (2) and m = 455, n = 204, p = 170 (3). Electrochemical characterization has been carried out both in solution and after electrochemical deposition onto platinum electrodes. The bioelectrocatalytical properties of electrodes modified with the polymers in the nicotinamide dinucleotide (NADH) and glucose oxidase (GOx) oxidations have been investigated as a function of the constitution and structure of the polymers. The analytical properties of electrodes modified with these polymers as sensors of NADH and GOx are described. In addition, an amperometric biosensor for glucose, prepared by electrostatic immobilization of glucose oxidase onto a platinum electrode modified with one of the ferrocenyl block-copolymers as an example, has been developed.

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Section: Electrochemical Behaviour Of the Copolymerssupporting

confidence: 88%

Section: Introductionmentioning

confidence: 99%

Electrochemical and bioelectrocatalytical properties of novel block-copolymers containing interacting ferrocenyl units

Armada¹,

Losada²,

López-Villanueva

et al. 2008

Journal of Organometallic Chemistry

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“…Until recently, synthetic difficulties associated with the creation of macromolecular chains possessing metal atoms as a key structural component have held back progress in the field. Over the past decade or so, these synthetic obstacles have been, in part, overcome through many creative procedures to prepare new materials [1,[20][21][22][23][24][25][26][27]. The new approaches that are now available have led to macromolecular structures in which metals are not only incorporated via the use of traditional covalent bonds but also by potentially reversible coordination interactions of comparable importance to these synthetic developments, these new materials have shown that they can possess a diverse range of interesting and useful properties and potential applications that complement those of organic macromolecules [1,[20][21][22][23][24][25][26][27].…”

Section: Organometallic Polymersmentioning

confidence: 99%

Organometallic Ferrocene- and Phosphorus-Containing Polymers: Synthesis and Characterization

Hussein

Asiri

2012

Designed Monomers and Polymers

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The inclusion of organometallic units into polymeric structures has attracted much attention in different fields according to the nature and behaviour of the inserted metal. Moreover, the discovery of organometallic polymers and their structural characterization initiated an explosive rebirth of organometallic chemistry. Organometallic moieties are in or pendent to the polymer backbone and examine some of the uses of the emergent metallocene polymers, and new uses are still being found for these remarkable organometallic moieties. This review gives a simple introduction to variable organometallic molecules and their characteristics. This review will focus on the syntheses and characterization of organometallic polymers, including ferrocene-and phosphorus-containing polymers. A general overview on ferrocene polymers with a special attention to ferrocene-containing liquid crystalline polymers (including a ferrocene moiety in the main chain, side-chain or dendrimers) and fullerene-ferrocene liquid crystalline polymers is presented. In addition, more details for synthesis and properties of phosphorus-containing polymers are illustrated.

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“…Living anionic polymerisation, and more recently ringopening metathesis polymerisation and "controlled" radical polymerisation, have played a key role in the development of BCP science. 86,[200][201][202][203][204][205][206][207][208][209] Synthetic routes to PFS-containing…”

Section: Rop Routes To Pfs Bcpsmentioning

confidence: 99%

Synthesis and Solution Self‐Assembly of Polyisoprene‐block‐poly(ferrocenylmethylsilane): A Diblock Copolymer with an Atactic but Semicrystalline Core‐Forming Metalloblock

Qiu

Winnik

et al. 2016

Macro Chemistry & Physics

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Organometallic Polymers with Transition Metals in the Main Chain

Cited by 825 publications

References 258 publications

Electrochemical and bioelectrocatalytical properties of novel block-copolymers containing interacting ferrocenyl units

Electrochemical and bioelectrocatalytical properties of novel block-copolymers containing interacting ferrocenyl units

Organometallic Ferrocene- and Phosphorus-Containing Polymers: Synthesis and Characterization

Synthesis and Solution Self‐Assembly of Polyisoprene‐block‐poly(ferrocenylmethylsilane): A Diblock Copolymer with an Atactic but Semicrystalline Core‐Forming Metalloblock

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