Overview of electrochemical competing process of sodium storage and metal plating in hard carbon anode of sodium ion battery

Zhou, Hanyu; Song, Yihang; Zhang, Boyang; Sun, Huanting; Khurshid, Iqbal Ahmed; Kong, Yanqiang; Chen, Lei; Cui, Liu; Zhang, Dongyue; Wang, Weijia; Yang, Lijun; Du, Xiaoze

doi:10.1016/j.ensm.2024.103645

Energy Storage Materials

2024

DOI: 10.1016/j.ensm.2024.103645

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Overview of electrochemical competing process of sodium storage and metal plating in hard carbon anode of sodium ion battery

Hanyu Zhou,

Yihang Song,

Boyang Zhang

et al.

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Cited by 3 publications

References 199 publications

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Electron Paramagnetic Resonance Monitoring of Sodium Clustering and Its Effect on the Sodium Storage of Biowaste-Derived Carbons

Kukeva,

Kalapsazova,

Harizanova

et al. 2024

ACS Appl. Energy Mater.

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Biowaste-derived carbons store large amounts of sodium as many competing reactions of adsorption, intercalation, and pore filling take place. Herein, we report electron paramagnetic resonance (EPR) spectroscopy as a comprehensive method to monitor the interaction of sodium with carbons used as electrodes in sodium-ion cells. It is shown that EPR can distinguish signals due to sodium intercalation and sodium cluster growth. Applying the correlation between the EPR line width and the metallic particle dimension, the sodium clusters are quantified regarding their size. In terms of the EPR, we discuss the sodiation mechanism and sodium storage performance of carbons derived from spent coffee grounds. The smallest sodium clusters (below 2 nm) are formed on closedpore carbons at a potential of 0.01 V, while the largest clusters (around 200 nm) occur on hydrogen-rich carbons at 0.05 V at the earliest. The small sodium clusters generated at around 0.01 V give extra capacity, while sodium intercalation occurring between 0.5 and 0.1 V ensures good cycle stability.

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Electron Paramagnetic Resonance Monitoring of Sodium Clustering and Its Effect on the Sodium Storage of Biowaste-Derived Carbons

Kukeva,

Kalapsazova,

Harizanova

et al. 2024

ACS Appl. Energy Mater.

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Probing sodium structures and dynamics in hard carbon for Na-ion batteries using ²³Na operando solid-state NMR spectroscopy

Gabrijelčič,

Tratnik,

Kapun

et al. 2025

J. Mater. Chem. A

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A Review of Carbon Anode Materials for Sodium-Ion Batteries: Key Materials, Sodium-Storage Mechanisms, Applications, and Large-Scale Design Principles

Jia,

Li,

Ruan

et al. 2024

Molecules

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Sodium-ion batteries (SIBs) have been proposed as a potential substitute for commercial lithium-ion batteries due to their excellent storage performance and cost-effectiveness. However, due to the substantial radius of sodium ions, there is an urgent need to develop anode materials with exemplary electrochemical characteristics, thereby enabling the fabrication of sodium-ion batteries with high energy density and rapid dynamics. Carbon materials are highly valued in the energy-storage field due to their diverse structures, low cost, and high reliability. This review comprehensively summarizes the typical structure; energy-storage mechanisms; and current development status of various carbon-based anode materials for SIBs, such as hard carbon, soft carbon, graphite, graphene, carbon nanotubes (CNTs), and porous carbon materials. This review also provides an overview of the current status and future development of related companies for sodium-ion batteries. Furthermore, it offers a summary and outlook on the challenges and opportunities associated with the design principles and large-scale production of carbon materials with high-energy-density requirements. This review offers an avenue for exploring outstanding improvement strategies for carbon materials, which can provide guidance for future application and research.

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Overview of electrochemical competing process of sodium storage and metal plating in hard carbon anode of sodium ion battery

Cited by 3 publications

References 199 publications

Electron Paramagnetic Resonance Monitoring of Sodium Clustering and Its Effect on the Sodium Storage of Biowaste-Derived Carbons

Electron Paramagnetic Resonance Monitoring of Sodium Clustering and Its Effect on the Sodium Storage of Biowaste-Derived Carbons

Probing sodium structures and dynamics in hard carbon for Na-ion batteries using ²³Na operando solid-state NMR spectroscopy

A Review of Carbon Anode Materials for Sodium-Ion Batteries: Key Materials, Sodium-Storage Mechanisms, Applications, and Large-Scale Design Principles

Contact Info

Product

Resources

About

Overview of electrochemical competing process of sodium storage and metal plating in hard carbon anode of sodium ion battery

Cited by 3 publications

References 199 publications

Electron Paramagnetic Resonance Monitoring of Sodium Clustering and Its Effect on the Sodium Storage of Biowaste-Derived Carbons

Electron Paramagnetic Resonance Monitoring of Sodium Clustering and Its Effect on the Sodium Storage of Biowaste-Derived Carbons

Probing sodium structures and dynamics in hard carbon for Na-ion batteries using 23Na operando solid-state NMR spectroscopy

A Review of Carbon Anode Materials for Sodium-Ion Batteries: Key Materials, Sodium-Storage Mechanisms, Applications, and Large-Scale Design Principles

Contact Info

Product

Resources

About

Probing sodium structures and dynamics in hard carbon for Na-ion batteries using ²³Na operando solid-state NMR spectroscopy