Oxidative Addition von H₂ und HCl an Iridium-Schwefelmonoxid- und Schwefeldioxid-Komplexe/ Oxidative Addition von H₂ und HCl an Iridium-Schwefelmonoxid- und Schwefeldioxid-Komplexe

Abstract

<jats:title>Abstract</jats:title><jats:p>Square planar iridium(I) complexes of sulfur monoxide and sulfur dioxide undergo oxidative addition with dihydrogen and hydrogen chloride. The resulting hydrido-iridium(III) complexes have been characterized by <jats:sup>1</jats:sup>H , <jats:sup>31</jats:sup>P NMR and IR spectroscopy. The limited stability of the sulfur monoxide derivatives is explained as resulting from decreased back-bonding between iridium and sulfur.</jats:p>

The coordination chemistry of small sulfur-containing molecules: a personal perspective

“…17). 54 They also add carbon monoxide to give bright green five-coordinated compounds 49 which are perfectly analogous to Vaska's SO 2 adduct. 55 These adducts readily release sulfur monoxide for M = Ir at 0 • C, for M = Rh at much lower temperature, which was trapped with 60 to 70% efficiency with an ortho-quinone (Fig.…”