Oxidative Couplings with C─H Bonds Forming C─P and C─S Bonds

Chen, Tieqiao; Han, Li‐Biao

doi:10.1002/9781119304197.ch13

Cited by 36 publications

(48 citation statements)

References 137 publications

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“…Venn diagram was generated using the R package VennDiagram. [89] These proteins are listed in Table 3 and the data sets underlying the Venn diagram are in Supporting Information 1. B) Functional enrichment analysis of the 12 common proteins using FungiFun [90] (https://elbe.hki-jena.de/fungifun/) revealed that all of the proteins were annotated as cell surface proteins and had functions in host interactions and carbohydrate metabolism.…”

Section: What Does the Future Hold For Research On Fungal Evs?mentioning

confidence: 99%

Fungal Extracellular Vesicles with a Focus on Proteomic Analysis

2019

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Extracellular vesicles (EVs) perform crucial functions in cell–cell communication. The packaging of biomolecules into membrane‐enveloped vesicles prior to release into the extracellular environment provides a mechanism for coordinated delivery of multiple signals at high concentrations that is not achievable by classical secretion alone. Most of the understanding of the biosynthesis, composition, and function of EVs comes from mammalian systems. Investigation of fungal EVs, particularly those released by pathogenic yeast species, has revealed diverse cargo including proteins, lipids, nucleic acids, carbohydrates, and small molecules. Fungal EVs are proposed to function in a variety of biological processes including virulence and cell wall homeostasis with a focus on host–pathogen interactions. EVs also carry signals between fungal cells allowing for a coordinated attack on a host during infection. Research on fungal EVs in still in its infancy. Here a review of the literature thus far with a focus on proteomic analysis is provided with respect to techniques, results, and prospects.

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Section: What Does the Future Hold For Research On Fungal Evs?mentioning

confidence: 99%

Fungal Extracellular Vesicles with a Focus on Proteomic Analysis

2019

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“…[199] The AAO templates were infiltrated by the metal eutectics using a setup that enabled evacuating the air from the pores, followed by hydraulic pressure injection of the melt into the pores. Single-crystal nanowires of Bi-Sn solder eutectic alloy were synthesized by confining its solidification within this porous structure.…”

Section: Effects Of Confinement Within the Templatementioning

confidence: 99%

“…Single-crystal nanowires of Bi-Sn solder eutectic alloy were synthesized by confining its solidification within this porous structure. [199,200] Given the direction of heat flow (from the top of the template to the bottom surface, where heat is extracted) and the expected solidification direction that results, alternating layers of the eutectic would ordinarily be expected to align along the axis of the cylindrical pores. The confined Bi-Sn eutectic melt phase-separated within these nanosized pores to form an alternating layer structure (Figure 10).…”

Section: Effects Of Confinement Within the Templatementioning

confidence: 99%

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Template‐Directed Solidification of Eutectic Optical Materials

Kulkarni

Kohanek

Tyler

et al. 2018

Advanced Optical Materials

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polarizers, some waveguides, and many lasers. [1][2][3] Materials with powerful optical functionalities, including negative-index of refraction and optical chirality, can be realized by appropriate placement of materials with suitable properties in 2D or 3D space. [4][5][6] Light in the visible spectrum can be manipulated, although the tolerance for defects is exceedingly low at visible frequencies, and the number of materials with the appropriate properties is limited. [7,8] Most photonic crystals are fabricated by high-resolution top-down 2D patterning methods such as electron-beam lithography, interference lithography, and focused ion beam milling. [9] However, it is challenging to fabricate large-area bulk materials with these techniques, especially with intricate internal structures. [8] Additionally, many materials with promising optical properties are not compatible with these top-down patterning methods. [4,10] As work on colloidal crystals has shown, controlled self-assembly is an effective route to organizing materials into 3D architectures, which interact strongly with light. [9][10][11][12][13] Colloidal self-assembly, however, only offers a limited set of symmetries (generally those of close packed arrangements), and a spherical basis. [12] For many applications, considerably more complex structures are of interest. Particularly promising approaches for forming materials with complex internal microstructures include eutectic solidification and block copolymer self-assembly, [14][15][16][17] and materials with interesting optical properties have been reported using both approaches. These methods are advantageous due to the wide range of microstructures they form. Here, we focus on the structures formed by eutectic solidification since materials with a broader range of optical properties are available compared to that provided by block copolymers, and because the characteristic lengths of structures accessible through eutectic solidification better match the wavelengths of visible and IR light. Further, forming materials with sufficiently large characteristic dimensions for interaction with visible light by block copolymer assembly is synthetically challenging as it requires high molecular weight polymers. [18] Similarly, self-assembly of other building blocks, e.g., nanoparticles, [19,20] molecules, [21,22] and DNA, [23,24] tend to produce structures with characteristic dimensions too small to provide strong light-matter interactions (via diffractive phenomena), [2,3,25] and are thus not the emphasis of this review.Mesostructured materials can exhibit enhanced light-matter interactions, which can become particularly strong when the characteristic dimensions of the structure are similar to or smaller than the wavelength of light. For controlling visible to near-infrared wavelengths, the small characteristic dimensions of the required structures usually demand fabrication by sophisticated lithographic techniques. However, these fabrication methods are restricted to producing 2D and a limited range of 3D...

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“…Compound 57 exhibited cytotoxicity towards Hep G2, A549, and MDA-MB-231 tumor cells with IC 50 's of 18.7, 18.5, and 15.2 μg/mL. [38]…”

Section: Sinularia Gibberosamentioning

confidence: 94%

Hydroperoxyditerpenoids from Octocorals

Sheu

Peng

Fang

et al. 2019

Israel Journal of Chemistry

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The structures, names, bioactivities, and references of 75 marine diterpenoids from octocorals possessing a hydroperoxy group, including 46 cembranes, 8 eunicellins, 5 briaranes, 5 dolabellanes, 4 germacranes, 3 xenicins, 2 caryophyllanes, 1 decalin, and 1 pseudopterosin, are summarized in this review article. All the hydroperoxyditerpenoids mentioned in this review were isolated from octocorals from Alcyonacea (Briareum excavatum, Briareum polyanthes, Briareum violaceum, Briareum sp., Cespitularia sp., Cladiella tuberculosa, Cladiella sp., Clavularia inflata, Klyxum simplex, Lemnalia sp., Lobophytum crassum, Lobophytum sp., Nephthea pacifica, Sarcophyton cherbonnieri, Sarcophyton crassocaule, Sarcophyton glaucum, Sarcophyton mililatensis, Sarcophyton trocheliophorum, Sarcophyton sp., Sinularia arborea, Sinularia erecta, Sinilaria flexibilis, Sinularia gibberosa, Sinularia manaarensis, Xenia umbellata) and Gorgonacea (Astrogorgia sp., Eunicea calyculata, Eunicea pinta, Eunicea succinea, Eunicea sp., Pseudopterogorgia sp.). Among these isolates, 41 compounds exhibited potential biomedical activities, including cytotoxicity, antimalarial activity, anti‐inflammatory activity, and antibacterial activity.

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Oxidative Couplings with C─H Bonds Forming C─P and C─S Bonds

Cited by 36 publications

References 137 publications

Fungal Extracellular Vesicles with a Focus on Proteomic Analysis

Fungal Extracellular Vesicles with a Focus on Proteomic Analysis

Template‐Directed Solidification of Eutectic Optical Materials

Hydroperoxyditerpenoids from Octocorals

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