Oxime‐Based Methods for Synthesis of Stereodefined Acyclic Polyfunctionalized δ‐Azido‐nitriles and 5‐Substituted Isoxazoles from Carbohydrate Derivatives.

Abstract

Carbohydrate derivatives such as 2-deoxysugar (I) and glycal (VI) are used as precursors in hydroxylamine-mediated syntheses of stereodefined polyfunctionalized δ-azido-nitriles like (V) and 5-substituted isoxazoles like (IX). -(PASSACANTILLI*, P.; PEPE, S.; PIANCATELLI*, G.; PIGINI, D.; SQUARCIA, A.; Tetrahedron 60 (2004) 31, 6453-6459; Dip. Chim., Univ. La Sapienza, CNR, I-00185 Roma, Italy; Eng.) -Bartels 47-175