Oxygen-phase-state changes in ZnS single crystals annealed in vapors of the constituents

Morozova, N. K.; Malov, M. M.; Veselkova, M. M.; Kurbatov, B. A.

doi:10.1007/bf00894002

Cited by 2 publications

(1 citation statement)

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“…Thus, the sphalerite is single crystal, and the compound is a multinary mixed phase, with the main impurities randomly distributed in the structure. Following the common practice [26,119,120], we applied the single-crystal XRD method to estimate the amount of oxygen in sphalerite.…”

Section: Trace-element Patterns Of CM Sphaleritementioning

confidence: 99%

Ultrahigh-Temperature Sphalerite from Zn-Cd-Se-Rich Combustion Metamorphic Marbles, Daba Complex, Central Jordan: Paragenesis, Chemistry, and Structure

et al. 2020

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Minerals of the Zn-Cd-S-Se system that formed by moderately reduced ~800–850 °C combustion metamorphic (CM) alteration of marly sediments were found in marbles from central Jordan. Their precursor sediments contain Se- and Ni-enriched authigenic pyrite and ZnS modifications with high Cd enrichment (up to ~10 wt%) and elevated concentrations of Cu, Sb, Ag, Mo, and Pb. The marbles are composed of calcite, carbonate-fluorapatite, spurrite, and brownmillerite and characterized by high P, Zn, Cd, U, and elevated Se, Ni, V, and Mo contents. Main accessories are either Zn-bearing oxides or sphalerite, greenockite, and Ca-Fe-Ni-Cu-O-S-Se oxychalcogenides. CM alteration lead to compositional homogenization of metamorphic sphalerite, for which trace-element suites become less diverse than in the authigenic ZnS. The CM sphalerites contain up to ~14 wt% Cd and ~6.7 wt% Se but are poor in Fe (means 1.4–2.2 wt%), and bear 100–250 ppm Co, Ni, and Hg. Sphalerite (Zn,Cd,Fe)(S,O,Se)cub is a homogeneous solid solution with a unit cell smaller than in ZnScub as a result of S2− → O2− substitution (a = 5.40852(12) Å, V = 158.211(6) Å3). The amount of lattice-bound oxygen in the CM sphalerite is within the range for synthetic ZnS1−xOx crystals (0 < x ≤ 0.05) growing at 900 °C.

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Section: Trace-element Patterns Of CM Sphaleritementioning

confidence: 99%