p-Doped high spin polymers1

Aqueous Electrolytes Based Dye-sensitized Solar Cells using I-/I3-Redox Couple to Achieve ≥ 4% Power Conversion Efficiency

“…The decrease of photocurrent may be attributable to the dye detachment, 7 formation of iodates, 6 and decrease in electron lifetime. 19 A similar phenomenon was observed in the previous work in an aqueous electrolyte.…”

“…N-Phenylation of aniline with 1-bromo-4-(2-(2-methoxyethoxy)ethoxy)benzene was performed under Ullmann′s condition, 19 followed by bromination to give 2. Suzuki coupling reaction 20 of 2 with 4,4,5,5-tetramethyl-2-(5-(5,5-dimethyl-1,3-dioxan-2-yl)thiophene-2-yl)-1,3,2-dioxaborolane led to 3.…”

Magnetic Ordering in an Organic Polymer

“…Because exchange interactions between electron spin through the -conjugated system can be made relatively strong, compared to the through-space interactions in molecular solids of organic radicals, this macromolecular approach has a potential for obtaining interesting magnetic properties at relatively high temperatures, even room temperature (7 ). Although significant progress has been made in the preparation of -conjugated oligomers and polymers with large values of spin quantum number S, organic polymer magnets have remained elusive (8)(9)(10)(11)(12)(13)(14)(15). We report the observation of magnetic properties comparable to that of insulating spin glasses and blocked superparamagnets in an organic -conjugated polymer.…”

Synthesis, characterization, and polymerization activity of (pentamethylcyclopentadienyl)titanatranes containing {(O-2,4-Me2C6H2-6-CH2)nN(CH2CH2O)3−n}3− (n=0–2) or {N(C6H4-2-O)3}3−

“…The distance between the Cp(centroid) and Ti ranges 2.136(2) Å for 2 and 2.036(10) Å for 4, which are similar to those observed for other structurally characterized (cyclopentadienyl)titanatrane complexes [4]. The Ti to Cp carbon distances, listed in Figs transannular Ti-N bond distance of 2.3176 (18) for 2 and 2.395(16) Å for 4 are similar to those observed for other structurally characterized titanium trialkanolamine derivatives [4,5,[8][9][10][11]. Other selected bond distances and angles are listed in Figs.…”

“…MAO was purchased in Witco. Compounds 1 [4], 2L-3L [9], and 4L [18] was synthesized by the literature procedure.…”