PP, ein Laborreagens?

Russell, Christopher A.

doi:10.1002/ange.201006243

Angewandte Chemie

2010

DOI: 10.1002/ange.201006243

|View full text |Cite

PP, ein Laborreagens?

Christopher A. Russell¹

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2013

2014

Publication Types

Select...

Article2

Relationship

Self Cite0

Independent2

Authors

Journals

Cited by 2 publications

(1 citation statement)

References 12 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Several non-aqueous electrolytes including; alkyl carbonates (propylene carbonate), ethers (tetraglyme and 1,3-dioxolane) and dimethylformamide [3][4][5] have been investigated for the Li-Air battery where electrolyte decomposition has been observed in all cases. The electrolytes are being consumed via a nucleophilic attack by the superoxide species at the electrophilic region of the electrolyte [3][4][5].…”

mentioning

confidence: 99%

A Multinuclear Solid State NMR Study of Potential Electrolytes for the Li-Air Battery

et al. 2013

View full text Add to dashboard Cite

show abstract

mentioning

confidence: 99%

A Multinuclear Solid State NMR Study of Potential Electrolytes for the Li-Air Battery

et al. 2013

View full text Add to dashboard Cite

show abstract

One-Electron-Mediated Rearrangements of 2,3-Disiladicarbene

et al. 2014

View full text Add to dashboard Cite

A disiladicarbene, (Cy-cAAC)2Si2 (2), was synthesized by reduction of Cy-cAAC:SiCl4 adduct with KC8. The dark-colored compound 2 is stable at room temperature for a year under an inert atmosphere. Moreover, it is stable up to 190 °C and also can be characterized by electron ionization mass spectrometry. Theoretical and Raman studies reveal the existence of a Si═Si double bond with a partial double bond between each carbene carbon atom and silicon atom. Cyclic voltammetry suggests that 2 can quasi-reversibly accept an electron to produce a very reactive radical anion, 2(•-), as an intermediate species. Thus, reduction of 2 with potassium metal at room temperature led to the isolation of an isomeric neutral rearranged product and an anionic dimer of a potassium salt via the formation of 2(•-).

show abstract

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

customersupport@researchsolutions.com

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

PP, ein Laborreagens?

Cited by 2 publications

References 12 publications

A Multinuclear Solid State NMR Study of Potential Electrolytes for the Li-Air Battery

A Multinuclear Solid State NMR Study of Potential Electrolytes for the Li-Air Battery

One-Electron-Mediated Rearrangements of 2,3-Disiladicarbene

Contact Info

Product

Resources

About