2010
DOI: 10.1016/j.cattod.2010.04.045
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Palladium-based bifunctional membrane reactor for one-step conversion of benzene to phenol and cyclohexanone

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Cited by 30 publications
(12 citation statements)
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“…Later on, Sato et al synthesized a number of Pd-based alloys and evaluated their properties in the conversions of benzene to phenol and cyclohexanone (see Figure 7 i). [ 105 ] Examples of Support Effects : As described in Section 4.2, integrating metal catalysts with appropriate supports may induce interfacial polarization to enhance oxygen activation (refer to Figure 6 c). This concept has been implemented in catalytic hydrocarbon oxidations.…”
Section: Carbon-hydrogen Bond Oxidationsmentioning
confidence: 99%
“…Later on, Sato et al synthesized a number of Pd-based alloys and evaluated their properties in the conversions of benzene to phenol and cyclohexanone (see Figure 7 i). [ 105 ] Examples of Support Effects : As described in Section 4.2, integrating metal catalysts with appropriate supports may induce interfacial polarization to enhance oxygen activation (refer to Figure 6 c). This concept has been implemented in catalytic hydrocarbon oxidations.…”
Section: Carbon-hydrogen Bond Oxidationsmentioning
confidence: 99%
“…Much progress in the last ten years has been achieved by using Pd membrane reactors. [183][184][185][186][187] Mizukami and co-workers reported that methyl benzoate can be directly hydroxylated to methyl salicylate 183 with a yield of 4.7% at 150 C; whereas the same reactor achieved benzene conversion of 15% and a phenol selectivity of 95%. Although the authors concede that an increase in reaction temperature caused undesired simultaneous hydrogenation.…”
Section: Oxidative Alkene Carboxylationmentioning
confidence: 99%
“…184 In a more recent work various active metals were loaded on the alpha-Al 2 O 3 porous tube which was the substrate of the thin Pd membrane. 186 This resulted in a number of side reactions, such as complete oxidation and hydrogenation, and a decrease in the hydroxylation activity. However, the loading of Cu suppressed complete oxidation and enhanced the hydroxylation activity.…”
Section: Oxidative Alkene Carboxylationmentioning
confidence: 99%
“…3.3 Catalytic membrane reaction under microwave radiation Pd membrane reactors have been investigated for various reactions, such as hydrogenation, dehydrogenation, and hydroxylation [14]. A catalytic membrane reactor combining a pore-filling Pd membrane with a microwave heating system was used for the hydrogenation of benzene and toluene at 423-493 K. The conversion is shown in Fig.…”
Section: Preparation Of Pd Membrane For Microwave Heatingmentioning
confidence: 99%