Palladium/norbornene/copper-catalysed intermolecular thio-esterification from ketones: modular access towards tetrasubstituted vinyl sulfides

Du, Guopeng; Zhao, Yu; Zhu, Pingliang; Ling, Shaowen; Xu, Baolong; Liu, Hui; Li, Xinjin; Sun, Feng-Gang

doi:10.1039/d3qo01484c

Org. Chem. Front.

2023

DOI: 10.1039/d3qo01484c

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Palladium/norbornene/copper-catalysed intermolecular thio-esterification from ketones: modular access towards tetrasubstituted vinyl sulfides

Guopeng Du,

Yu Zhao,

Pingliang Zhu

et al.

Abstract: A Catellani-type α-alkoxycarbonylation/ipso-thiolation of enol triflates from ketones to access diverse tetrasubstituted vinyl sulfides has been developed.

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2024

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Cited by 2 publications

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Palladium-Catalyzed Dual C–H Arylation/Cyclization Reaction of Iodoferrocenes with ortho-Bromobenzamides for the Construction of Arylated Isoquinolone-Fused Ferrocenes

Li,

Fan

et al. 2024

J. Org. Chem.

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We reported a palladium/norbornene-catalyzed dual intermolecular C−H arylation/intramolecular cyclization reaction of iodoferrocenes with ortho-bromobenzamides, enabling the formation of arylated isoquinolone-fused ferrocenes in a straightforward and effective manner. This method has a broad substrate scope and good functional group compatibility, while the gram-scale reaction demonstrates the practicality of this method.

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Palladium-Catalyzed Dual C–H Arylation/Cyclization Reaction of Iodoferrocenes with ortho-Bromobenzamides for the Construction of Arylated Isoquinolone-Fused Ferrocenes

Li,

Fan

et al. 2024

J. Org. Chem.

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Transition metal-free synthesis of polyfluoroaryl sulfides via S-transfer reaction

Wang,

Liu,

Zhou

et al. 2024

Org. Chem. Front.

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Palladium/norbornene/copper-catalysed intermolecular thio-esterification from ketones: modular access towards tetrasubstituted vinyl sulfides

Abstract: A Catellani-type α-alkoxycarbonylation/ipso-thiolation of enol triflates from ketones to access diverse tetrasubstituted vinyl sulfides has been developed.

Cited by 2 publications

References 66 publications

Palladium-Catalyzed Dual C–H Arylation/Cyclization Reaction of Iodoferrocenes with ortho-Bromobenzamides for the Construction of Arylated Isoquinolone-Fused Ferrocenes

Palladium-Catalyzed Dual C–H Arylation/Cyclization Reaction of Iodoferrocenes with ortho-Bromobenzamides for the Construction of Arylated Isoquinolone-Fused Ferrocenes

Transition metal-free synthesis of polyfluoroaryl sulfides via S-transfer reaction

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