2023
DOI: 10.1002/chem.202301637
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Pd‐Catalyzed Tandem Pathway for Stereoselective Synthesis of (E)‐1,3‐Enyne from β‐Nitroalkenes by Using a Sacrificial Directing Group

Abstract: The involvement of nitroalkenes instead of minimal one alkyne motif for (E)‐1,3‐enynes synthesis through a palladium catalyzed stereo‐selective bond forming pathway at room temperature is presented. Implication of nitro group as a sacrificial directing group, formation of magical alkyne on a newly developed Csp3‐Csp3 bond with initial palladium‐MBH adduct make this methodology distinctive. This protocol features an unprecedented sequential acetate addition, carbon‐carbon bond formation, isomerization of double… Show more

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References 80 publications
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