Pd/NHC catalyzed reduction and coupling of nitroaromatics for the synthesis of diarylamines

Chen, Wei; Chen, Kai; Wang, Xuejie; Yang, Linjie; Chen, Wanzhi

doi:10.1039/d4ra00921e

RSC Adv.

2024

DOI: 10.1039/d4ra00921e

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Pd/NHC catalyzed reduction and coupling of nitroaromatics for the synthesis of diarylamines

Wei Chen,

Kai Chen,

Xuejie Wang

et al.

Abstract: Pd/NHC catalyzes the one-pot synthesis of diarylamine compounds from nitroarenes, by introducing triethylsilane as a reducing agent.

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Cited by 2 publications

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Denitrative Functionalization of Nitroarenes: Recent Progress and Future Perspectives

Li,

Lei,

Yang

et al. 2024

Eur J Org Chem

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Nitroarenes are fundamental feedstocks in the chemical industry. Their relatively inert C−NO2 bond allows for late‐stage modifications of molecules and exhibits complete orthogonality to the reactivity of C−halogen bond in cross‐coupling reactions. The denitrative functionalization of nitroarenes holds significant appeal due to it avoids the use of aryl halides, thereby simplifying reaction steps and improving atom and step economy. Recent progress in direct denitrative functionalization of nitroarenes includes palladium‐catalyzed denitrative coupling, copper‐catalyzed denitrative coupling, as well as metal‐free one‐pot C−NO2 functionalization. In this review, we provide a concise overview of these advancements, detailing the reaction features and mechanisms. This summary aims to highlight the versatility and efficiency of denitrative functionalization methodologies, offering insights into their potential applications and inspiring further research in this promising area of organic synthesis.

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Denitrative Functionalization of Nitroarenes: Recent Progress and Future Perspectives

Li,

Lei,

Yang

et al. 2024

Eur J Org Chem

View full text Add to dashboard Cite

show abstract

Transition-metal-free photochemical reductive denitration of nitroarenes

Tang,

Xu,

Zhang

2024

Chem. Commun.

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Pd/NHC catalyzed reduction and coupling of nitroaromatics for the synthesis of diarylamines

Abstract: Pd/NHC catalyzes the one-pot synthesis of diarylamine compounds from nitroarenes, by introducing triethylsilane as a reducing agent.

Cited by 2 publications

References 31 publications

Denitrative Functionalization of Nitroarenes: Recent Progress and Future Perspectives

Denitrative Functionalization of Nitroarenes: Recent Progress and Future Perspectives

Transition-metal-free photochemical reductive denitration of nitroarenes

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