Pentafluorosulfanyl-functionalised BODIPY push–pull dyes for p-type dye-sensitized solar cells

James, Richard; Alqahtani, Linah S.; Mallows, John; Flint, Heather; Waddell, Paul G.; Woodford, Owen J.; Gibson, Elizabeth A.

doi:10.1039/d2se00977c

Cited by 8 publications

(4 citation statements)

References 34 publications

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“…Push-pull chromophores have been extensively studied in recent years with the aim of incorporating them into the conception of organic solar cells [60], mainly as donor materials. Among various solar cell technologies, their use in dye-sensitized solar cells (DSSCs) has revealed interesting results since such donor-π-acceptor (D-π-A) sensitizers exhibit strong molar absorption, making it possible to use thin oxide films compatible with the improvement in the open circuit voltage [61][62][63][64][65]. The operating principle of DSSCs incorporating push-pull assemblies at inorganic oxide surfaces is depicted in Figure 3, extracted from the recent article by D'Annibale et al [66].…”

Section: Sams From Push-pull Chromophores For Dye-sensitized Solar Ce...mentioning

confidence: 99%

Self-Assembled Monolayers of Push–Pull Chromophores as Active Layers and Their Applications

Wang,

Gadenne,

Patrone

et al. 2024

Molecules

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In recent decades, considerable attention has been focused on the design and development of surfaces with defined or tunable properties for a wide range of applications and fields. To this end, self-assembled monolayers (SAMs) of organic compounds offer a unique and straightforward route of modifying and engineering the surface properties of any substrate. Thus, alkane-based self-assembled monolayers constitute one of the most extensively studied organic thin-film nanomaterials, which have found wide applications in antifouling surfaces, the control of wettability or cell adhesion, sensors, optical devices, corrosion protection, and organic electronics, among many other applications, some of which have led to their technological transfer to industry. Nevertheless, recently, aromatic-based SAMs have gained importance as functional components, particularly in molecular electronics, bioelectronics, sensors, etc., due to their intrinsic electrical conductivity and optical properties, opening up new perspectives in these fields. However, some key issues affecting device performance still need to be resolved to ensure their full use and access to novel functionalities such as memory, sensors, or active layers in optoelectronic devices. In this context, we will present herein recent advances in π-conjugated systems-based self-assembled monolayers (e.g., push–pull chromophores) as active layers and their applications.

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Section: Sams From Push-pull Chromophores For Dye-sensitized Solar Ce...mentioning

confidence: 99%

Self-Assembled Monolayers of Push–Pull Chromophores as Active Layers and Their Applications

Wang,

Gadenne,

Patrone

et al. 2024

Molecules

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“…BODIPY centered dyes reported for p-DSSCs. [118,119] properties. Cutting-edge theoretical analysis, employing DFT and TDDFT, provided valuable insights into how the chemical composition and structure influenced these dyes' electronic characteristics.…”

Section: Literature Reports On P-type Organic Sensitizersmentioning

confidence: 99%

“…In 2023, Gibson and colleagues [ 119 ] delved into investigating BODIPY‐based dyes functionalized with an electronegative SF5 group at the mesoposition. The molecular structures of these dyes are depicted in Figure 21.…”

Section: Molecular Design Of P‐type Metal‐free Organic Sensitizersmentioning

confidence: 99%

Metal‐Free Organic Dyes for NiO‐Based Dye‐Sensitized Solar Cells: Recent Developments and Future Perspectives

Naik,

Elias,

Keremane

et al. 2024

Energy Tech

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The increasing global demand for energy and growing environmental concerns emphasize the crucial role of solar energy as a sustainable and nondepletable resource. Solar cells, particularly dye‐sensitized solar cells (DSSCs), have gained prominence due to their efficient conversion of solar power, ecofriendly manufacturing processes, and noteworthy stability. Current research in sustainable energy focuses on transitioning from metal‐based to metal‐free organic materials. Tandem solar cells, combining n‐type and p‐type semiconductors sensitized with diverse photoactive dyes, show potential to surpass thermodynamic limits in photon conversion efficiency. Notably, the exploration of n‐type DSSCs as photoanodes in tandem architectures is promising. However, the absence of efficient p‐type photoactive cathodes remains a significant obstacle. Global research efforts are dedicated to addressing charge recombination issues in NiO‐based devices to enhance the efficiency of p‐type DSSCs. The success of any DSSC hinges on the selection of dyes/sensitizers with suitable anchoring groups, wide absorption in the visible–NIR region, and a high extinction coefficient. This article comprehensively reviews advancements in developing highly efficient p‐type sensitizers, emphasizing their pivotal role in unlocking the full potential of tandem solar cells.

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“…BD1, BD4 and its corresponding dicarboxylic acid (BD4-CO2H, able to bind to NiO) have also been studied by Gibson in tandem dye-sensitized solar cells with a photoactive electrode. 60 Improved properties imparted by the SF5 substituent originate from the extended charge separation lifetime within the dyes, which reduces recombination and increase current flow. However, molecular design still needs to be improved to deliver dyes that are competitive with the current standard of the field.…”

Section: Materials Sciencementioning

confidence: 99%

Recent Advances in the Chemistry and Application of SF5-Compounds

Bizet,

Abd El Sater,

Popek

et al. 2024

Synthesis

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This review article outlines the literature covering last three years on the recent developments of the SF5 chemistry. Recent synthesis methodologies of SF5-containing building blocks are reported. These methods include the synthesis of SF5Cl, its use in pentafluorosulfanylation reactions, and oxidative fluorination reactions. Moreover, the reactivity of SF5-alkynes as versatile platform to access new SF5-compounds is described. Finally, effect of SF5 moiety is highlighted according to its application in different fields such as biological/medicinal chemistry, catalysis and material sciences.

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Pentafluorosulfanyl-functionalised BODIPY push–pull dyes for p-type dye-sensitized solar cells

Abstract: NiO-based photocathodes are being developed for use in tandem dye-sensitized solar cells (DSSCs) and photoelectrocatalytic devices for splitting water. To capture and convert as much of solar spectrum as efficiently...

Cited by 8 publications

References 34 publications

Self-Assembled Monolayers of Push–Pull Chromophores as Active Layers and Their Applications

Self-Assembled Monolayers of Push–Pull Chromophores as Active Layers and Their Applications

Metal‐Free Organic Dyes for NiO‐Based Dye‐Sensitized Solar Cells: Recent Developments and Future Perspectives

Recent Advances in the Chemistry and Application of SF5-Compounds

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