Photosensitive polyacetylenes

Polymerization by oxidative coupling: Discovery and commercialization of PPO� and Noryl� resins

“…When the tive and could be cross-linked by irradiation with commercial development of PPO began in 1960 a UV light. 54,55 major priority was the development of a monomer Oxidative coupling was also used for the synprocess. 2,6-Dimethylphenol was available only thesis of poly(disulfide)s, 56 the catalytic oxidaas a byproduct from coal tar distillation and retion of hydrogen sulfide, 57 the synthesis of benzoquired the development of a purification process.…”

A Highly Immobilized Organic Anode Material for High Performance Rechargeable Lithium Batteries

“…Route A: general nucleophilic substitution synthetic routes of Li 2 (BPy-bdc) First, we tried to prepare Li 2 (BPy-bdc) using the reported general procedure (route A) as follows: DHTPA (4.0 g, 20 mmol, ≥98%, Aladdin) and potassium carbonate (K 2 CO 3 ) (12.6 g, 91 mmol, Aladdin) were dispersed in 160 mL of N , N -dimethyl­formamide (DMF) under stirring, to which propargyl bromide (5.2 g, 44 mmol, Aladdin) was added drop by drop.…”

Topochemical Polymerization: Diynes

“…This was observed first for diynoic acid films.'" 112,113 These early findings went largely unnoticed but were extended by Patel et al 1 14 These studies of polyurethane-diyne copolymers have been considerably extended by the work of Rubner and co-workers.H" -117 He reported the synthesis of a range of segmented' copolymers and their characterization by differential scanning calorimetry, and IR and visible spectroscopy. 9 6 , 9 7 Both phospholipids and lipids containing diynes have been shown to polymerize?"…”