When compared with two conformal phosphor and in-cup phosphor structures, the remote phosphor structure has higher luminescent performance. However, it is difficult to control the color quality of the remote phosphor structure, so it has become a research target in recent years. So far, there are two remote phosphor structures used to improve color quality including dual-layer phosphor configuration and triple-layer phosphor configuration. This study suggests using those two configurations to make multi-chip white LEDs (WLEDs) that can achieve adequate values in color rendering index (CRI), color quality scale (CQS), luminous efficacy (LE) and color uniformity. WLEDs with a color temperature of 5600 K are applied. Research results show that the triple-layer phosphor configuration is superior in CRI, CQS, LE. Besides, the color deviation decreases significantly, meaning that the color homogeneity increases with the triple-layer phosphor configuration. This can be demonstrated by analyzing the scattering characteristics of phosphor classes through Mie theory, thus making the research results more reliable and valuable for producing quality WLEDs. This is an Open Access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium provided the original work is properly cited.