Planarizing Distortions in Polycyclic Carbon Compounds

Keese, Reinhart; Luef, Wolfgang; Mani, Jürg; Schüttel, Stefan; Schmid, M.; Zhang, C.

doi:10.1007/978-94-009-0929-8_20

Strain and Its Implications in Organic Chemistry 1989

DOI: 10.1007/978-94-009-0929-8_20

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Planarizing Distortions in Polycyclic Carbon Compounds

Reinhart Keese

Wolfgang Luef

Jürg Mani

et al.

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2024

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Cited by 2 publications

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Synthesis, Structural Features and Fluorescent Properties of Terbium Acylpyrazolone Complexes

Travadi,

Jadeja,

Butcher

2024

ChemistrySelect

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Three 8‐coordinated terbium acylpyrazolone complexes [Tb(DMBPMP)3(H2O)2] (Tb1), [Tb(DMBMCPMP)3(H2O)2] (Tb2), and [Tb(DMBPTMP)3(H2O)2] (Tb3) with a distorted bicapped trigonal prismatic structure were synthesized (where, 3,5‐dimethylbenzoyl 1‐(phenyl = DMBPMP/m‐chlorophenyl = DMBMCPMP/p‐tolyl = DMBPTMP) 3‐methyl 5‐pyrazolone). The structures of the complexes were comprehensively analyzed using mass ESI, FTIR, UV–vis, powder XRD, and TG‐DTA methods. Single‐crystal analysis of Tb3·H2O confirmed an eight‐coordinate structure (TbO8) with a distorted bicapped trigonal prismatic geometry. In the on‐state emission spectrum, the 5D4 → 7F5 transition exhibits hypersensitivity in the green region of the visible spectrum (∼540–560 nm). The differences between electric dipole (ED) and magnetic dipole (MD) transitions indicate a small degree of asymmetry. The examination of solid‐state emission spectra included the assessment of intensity, G/B ratio, green color purity, and the antenna effect energy diagram.

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Synthesis, Structural Features and Fluorescent Properties of Terbium Acylpyrazolone Complexes

Travadi,

Jadeja,

Butcher

2024

ChemistrySelect

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Fluorescent and electronic properties of Dysprosium acylpyrazolone complexes along with their synthesis and structural features

Travadi,

Jadeja,

Butcher

2024

Polyhedron

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Planarizing Distortions in Polycyclic Carbon Compounds

Cited by 2 publications

References 25 publications

Synthesis, Structural Features and Fluorescent Properties of Terbium Acylpyrazolone Complexes

Synthesis, Structural Features and Fluorescent Properties of Terbium Acylpyrazolone Complexes

Fluorescent and electronic properties of Dysprosium acylpyrazolone complexes along with their synthesis and structural features

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