POE‐Mediated Tunable Quantum Yield of Carbon Dots−Derived From Agapanthus Africanus (L.) Hoffmann Leaves

Abstract

The green synthesis of carbon dots (CDs) from natural sources is a challenging goal. Herein CDs are produced from Agapanthus africanus (L.) Hoffmann leaves by carbonization at 200/300 °C for 2/3 h. Samples are named CZ‐X‐Y, where Z, X, and Y represent carbonization, temperature, and time, respectively. CZ‐200‐3, CZ‐300‐2, and CZ‐300‐3 CDs have average sizes of 3.7 ± 0.7, 5.3 ± 1.2, and 5.1 ± 1.6 nm, respectively. Their surface, devoid of chlorophyll, contains ─OH, ─C═O, and ─C(═O)OH groups and sylvite. Isolated CZ‐300‐3 emits at 400 nm (excited at 260 nm) and exhibits an emission quantum yield (QY) value of 2 ± 1%. Embedding in the d‐U(600)/d‐(900) di‐ureasil matrices resulted in transparent films with emission intensity maxima at 420/450 nm (360 nm), and QY values of 7 ± 1/16 ± 2% (400 nm). The enhancement of the QY value of the bare CDs agrees with an efficient passivation provided by the hybrid host. The hydrophilic CZ‐300‐3 CDs also exerted a marked surface modifying role, changing the surface roughness and the wettability of the hybrid films.