1984
DOI: 10.1088/0022-3700/17/1/012
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Polarisation effects in time-resolved laser-induced fluorescence experiments

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Cited by 8 publications
(9 citation statements)
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“…To understand the mechanism and dynamics of reactions involving Hg atoms, much efforts have been devoted to the simple gas phase reactions Hg͑ 1 S 0 , 3 P 1 ͒ +H 2 → HgH+ H. [9][10][11][12][13][14][15][16] It is generally believed that the insertion of Hg͑ 3 P 1 ͒ into the H-H bond leads to the H-Hg-H complex in both the 3 AЈ and 1 AЈ states, due to strong spin-orbit coupling of the mercury atom. 5,16,17 In fact, a stable HgH 2 compound has been observed recently in H 2 matrices and in mixed H 2 /Ar or H 2 /N 2 matrices.…”
Section: Introductionmentioning
confidence: 99%
“…To understand the mechanism and dynamics of reactions involving Hg atoms, much efforts have been devoted to the simple gas phase reactions Hg͑ 1 S 0 , 3 P 1 ͒ +H 2 → HgH+ H. [9][10][11][12][13][14][15][16] It is generally believed that the insertion of Hg͑ 3 P 1 ͒ into the H-H bond leads to the H-Hg-H complex in both the 3 AЈ and 1 AЈ states, due to strong spin-orbit coupling of the mercury atom. 5,16,17 In fact, a stable HgH 2 compound has been observed recently in H 2 matrices and in mixed H 2 /Ar or H 2 /N 2 matrices.…”
Section: Introductionmentioning
confidence: 99%
“…For several cases, studied in our laboratories 21,[24][25][26]28,29,32,33,37,62 as well as in others, 30,44,45,47,48,53,54,62 detailed quantum-state resolved distributions of the vibrational and rotational energy of the MH(v,N) products in exit-channel ͑1a͒ have also been determined using laser pump-probe techniques. A variety of mechanisms, 1-62 at various levels of detail, have been proposed over the years to explain both the dominant products observed ͓͑1a͒, ͑1b͒, or ͑1c͔͒ and the distributions of MH(v,N) energies when process ͑1a͒ occurs.…”
Section: Introductionmentioning
confidence: 99%
“…For example, for alkali atoms, the 2 P J doublet states mix with cross sections, typically of 100 A 2 or more [359,360]. Similar studies have been performed for Hg [297,298] as well as Ga and Tl [361]. Nevertheless, in some situations, fine-structure splitting and collisional transfer can play a role in the selection of detection schemes.…”
Section: Quenching and Energy Transfermentioning
confidence: 78%
“…Fluorescence was detected in the regions 312.5e313.2, 577e580 and 365e366 nm, respectively. Bras et al [298] excited Hg to the 7s 1 S 0 state using two 312.8 nm photons and detected direct fluorescence at 407.8 nm or collisionally induced fluorescence at 404.7. However, these studies actually focussed on collisional effects and LODs were not evaluated.…”
Section: Laser Induced Fluorescencementioning
confidence: 99%
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