The consequences of a recently introduced irreducible pionic effect in low energy nucleon-deuteron scattering are analyzed. Differential cross-sections, nucleon (vector) and deuteron (vector and tensor) analyzing powers, and four different polarization transfer coefficients have been considered. This 3N F -like effect is generated by the pion-exchange diagram in presence of a two-nucleon correlation and is partially cancelled by meson-retardation contributions. Indications are provided that such type of effects are capable to selectively increase the vector (nucleon and deuteron) analyzing powers, while in the considered energy range they are almost negligible on the differential cross sections. These indications, observed with different realistic nucleonnucleon interactions, provide additional evidences that such 3N F -like effects have indeed the potential to solve the puzzle of the vector analyzing powers. Smaller but non negligible effects are observed for the other spin observables. In some cases, we find that the modifications introduced by such pionic effects on these spin observables (other than the vector analyzing powers) are significant and interesting and could be observed by experiments.PACS numbers: 24.70+s, 21.30.Cb, 25.10.+s, 25.40.Dn, 21.45.+v, and 13.75.Cs