Poly[[aquatris(μ-dimethyl phosphato-κ²O,O′)bis(μ-dimethyl sulfoxide-κO)(dimethyl sulfoxide-κO)dimanganese(II)] nitrate monohydrate]

Abstract

Key indicatorsSingle-crystal X-ray study T = 120 K Mean (O-N) = 0.006 Å R factor = 0.049 wR factor = 0.090 Data-to-parameter ratio = 18.4For details of how these key indicators were automatically derived from the article, see

[Bis(2,6-diisopropylphenyl) phosphato-κO]pentakis(methanol-κO)manganese bis(2,6-diisopropylphenyl) phosphate methanol trisolvate

“…Thus, the number of structures in the Cambridge Structural Database (CSD version 5.38, latest update May 2017; Groom et al, 2016) is limited to 20 (after the exclusion of duplicated structures). These comprise: one mononuclear complex (MOKCEU; Murugavel & Sathiyendiran, 2001); four binuclear complexes [DAVFEM (Shiraishi et al, 2005), ENIMUJ (Yashiro et al, 2003), YIWYUA and YIWZAH (Pothiraja et al, 2014) (Bian et al, 2004;Kuroda-Sowa et al, 2005) and XUBXOH/XUBXOH01 (Kuroda-Sowa et al, 2002]; eight coordination polymers [KOZZAC and KOZZUW (Rajakannu et al, 2015), LULGEE (Sathiyendiran & Murugavel, 2002), ODEWOK (Rafizadeh et al, 2007), SAMNEA/SAMNEA01 (Pothiraja et al, 2004(Pothiraja et al, , 2005, TEKQOR and TEKQUX (Dey et al, 2013) and WENSUE (Rafizadeh et al, 2006)]. All of the above are heteroleptic complexes containing the following di-substituted organophosphate ligands:…”

Tris(ethylenediamine-κ2N,N′)nickel(II) bis(dimethyl phosphate)

“…For related structures, see: Amani et al (2006); Jun & Zhang (2010); Rafizadeh & Amani (2006a,b, 2007; Rafizadeh, Amani & Aghayan (2006); Rafizadeh, Amani & Broushaky (2006); Rafizadeh, Hoseinzadeh & Amani (2006); Rafizadeh et al (2005Rafizadeh et al ( , 2009.…”

“…Data collection: X-AREA (Stoe & Cie, 2002); cell refinement: X-AREA; data reduction: X-RED (Stoe & Cie, 2002); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: ORTEP-3 (Farrugia, 1997); software used to prepare material for publication: WinGX (Farrugia, 1999 (Rafizadeh et al, 2005) (Rafizadeh, Hoseinzadeh & Amani, 2006) (Rafizadeh, Amani, & Aghayan, 2006), [Ce 2 (µ-DEP) 6 (TEP)] n (Amani et al, 2006) , [Nd(µ-DEP) 3 ] n and [Pr(µ-DMP) 2 (µ-NO 3 )(DMSO)] n (Rafizadeh et al, 2009) (DMSO = dimethylsulfoxide, DEP = diethylphosphate and TEP = triethylphosphate). DMP and DEP act as O-donor ligands, thus forming coordination polymers in solid state.…”