Poly-Lactide/Exfoliated C30B Interactions and Influence on Thermo-Mechanical Properties Due to Artificial Weathering

Abstract

Thermal stability as well as enhanced mechanical properties of poly-lactide (PLA) can increase PLA applications for short-use products. The conjunction of adequate molecular weight (M W ) as well as satisfactory thermo-mechanical properties, together, can lead to the achievement of suitable properties. However, PLA is susceptible to thermal degradation and thus an undesired decay of M W and a decrease of its mechanical properties during processing. To avoid this PLA degradation, nanofiller is incorporated as reinforcement to increase its thermo-mechanical properties. There are many papers focusing on filler effects on the thermal stability and mechanical properties of PLA/nanocomposites; however, these investigations lack an explanation of polymer/filler interactions. We propose interactions between PLA and Cloisite30B (C30B) as nanofiller. We also study the effects on the thermal and mechanical properties due to molecular weight decay after exposure to artificial weathering. PLA blank and nanocomposites were subjected to three time treatments (0, 176, and 360 h) of exposure to artificial weathering in order to achieve comparable materials with different M W . M W was acquired by means of Gel Permeation Chromatography (GPC). Thermo-mechanical properties were investigated through Thermogravimetric Analysis (TGA), Differential Scanning Calorimetry (DSC), X-ray Diffraction (XRD), Dynamic Mechanical Thermal Analysis (DMTA) and Fourier Transform Infrared Spectroscopy (FTIR).

Supercritical CO2 deposition and foaming process for fabrication of biopolyester–ZnO bone scaffolds

“…The optimization of this process is, however, challenging regarding nanolevel dispersion of particles and ensuring structural integrity of the nanofillers . Apart from that, the processing method and temperature regime should have minimal adverse effects on the PLA matrix which is prone to degradation above 180 °C …”