Polyethersulfone mixed matrix membranes modified with pore formers and Ag-titanate nanotubes: physicochemical characteristics and (bio)fouling study

Abstract

In the presented studies it was hypothesized that the modification of a polymeric membrane with a pore former and a hybrid nanomaterial composed of titanate nanotubes with deposited Ag nanoparticles (Ag-TNTs NPs) can protect the membrane from the microbial growth, and thus enhance its resistance to biofouling. Polyethersulfone (PES) membranes were prepared by the wet phase inversion, and polyvinylpyrrolidone (PVP) and poly(ethylene glycol) (PEG) were used as pore formers. The membranes were characterized in terms of morphology, topography, permeability, separation characteristics, and anti-(bio)fouling properties as well as antibacterial activity. The membranes modified with porogens and Ag-TNTs revealed improved hydrophilicity and water permeability compared to the unmodified membrane, from 58 to 66%. Moreover, the improvement in rejection of model dextrans and PEG upon application of the NPs was found. However, the use of PVP or PEG had a negative influence on the resistance to fouling by bovine serum albumin, i.e., ca. 35% of decline of permeate flux was noticed after 2 h of ultrafiltration of BSA. On the contrary, both porogens and NPs contributed to biofouling mitigation. The introduction of pore formers had a positive effect on the inhibition of Escherichia coli growth by the membrane containing Ag-TNTs. The log reduction of bacteria varied from 3.17 to 3.3 in case of stirred and filtration system.