2000
DOI: 10.1007/s002890070064
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Polymer-metal complexes: Synthesis, characterization, and properties of poly(maleic acid) metal complexes with Cu(II), Co(II), Ni(II), and Zn(II)

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Cited by 40 publications
(18 citation statements)
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“…Hydrogels have numerous applications in different fields; they can be used to remove toxic substances from the environment [2][3][4], and also as biomaterials for tissue regeneration [5] as well as for controlled release of bioactive substances [6]. On the other hand, metal ions can interact with polymers to form polychelates [7]. The presence of metal ions in the polychelates can modify the properties of the polymer as a function of the type of metal ion included as well as its concentration [8].…”
Section: Introductionmentioning
confidence: 99%
“…Hydrogels have numerous applications in different fields; they can be used to remove toxic substances from the environment [2][3][4], and also as biomaterials for tissue regeneration [5] as well as for controlled release of bioactive substances [6]. On the other hand, metal ions can interact with polymers to form polychelates [7]. The presence of metal ions in the polychelates can modify the properties of the polymer as a function of the type of metal ion included as well as its concentration [8].…”
Section: Introductionmentioning
confidence: 99%
“…The conductivity decreased as amount of metal binding in complex structure increases. In similar studies, conductivity values are very low at room temperatures, but when the temperature rises above 100 ∘ C, the molecule also loses water and conductivity of the metal complexes increases in which the metal complexes behave as semiconductors [25,47]. The conductivity values of the ligand containing 13% DEAMSt, as seen in Figure 13, were lower.…”
Section: Dielectrical Propertiesmentioning
confidence: 76%
“…In this case, the ionic character between the functional groups of ligands and metal ions is very high. In similar studies, when activation energies are decreased, ion transport number and conductivity increased, and the complexes at high temperature regions continue the superionic structure [47,49].…”
Section: Dielectrical Propertiesmentioning
confidence: 81%
“…There have been many reports in the literature relevant to their synthesis, structure, and properties. These complexes were successfully prepared on the basis of poly (vinyl alcohol) [6], poly(malic acid) [7], poly(acrylic acid) [8], poly(ethyleneimine) [9], poly (2-hydroxy-4-acryloyloxy acetophenone formaldehyde) [10] and other polymers and monomers [11,12]. Transition metal ions which are usually involved in these reactions are Cu(II), Zn(II), Co(II), Co(III), Fe(II), Fe(III), Ni(II).…”
Section: Introductionmentioning
confidence: 99%