Polymeric thiolate complexes of Group 12 metals. Crystal and molecular structures of catena-[µ-(3-dimethylammonio-1-propanethiolate)]-dichloro-cadmium(II) and bis[3-(dimethylammonio)propyl] disulphide tetrabromocadmate(II)

Abstract

Polymeric Thiolate Complexes of Group 12 tMetals. Crystal and Molecular Structures of catena-[ p-(3-Di methylammonio-I -propanethiolate)] -dichlorocadmium (11) and B is[ 3-(d i met hylammonio) propyl] Disulphide Tetrabromocadmate(ii) 4 lsidre Casals,

Two Cyano‐Functionalized, Cadmium‐Containing Ionic Liquids

“…The asymmetric unit contains one [CdCl 4 ] 2– anion and two 3‐cyanomethyl‐1‐methylimidazolium ([CMMIM] + ) cations. The Cd–Cl distances in the CdCl 4 tetrahedron range from 2.428(2) to 2.483(2) Å, and the Cl–Cd–Cl angles range from 103.13(6) to 114.29(6)° (see Table 1), which are all comparable to those found in other CdCl 4 ‐containing compounds 18–19. No interaction of the cyano group with the cadmium cation is found, as the chloride anion is the stronger Lewis base.…”

Bis[4-(trimethylammonio)phenyl] disulfide tetraiodomercurate(II)

“…The Tab-Tab dication has positive charges located on the NMe 3 groups. The torsion angle about the SÐS bond [C1Ð S1ÐS2ÐC10] is 92.1 (3) , which is larger than those reported in Cargill Thompson et al, 1997], [C 5 H 9 NH(CH 3 )S] 2 CuCl 4 (90 ; Brianso  et al, 1981) and [{(CH 3 ) 2 HN(CH 2 ) 3 } 2 ][CdBr 4 ] (75.4 ; Casals et al, 1987). The SÐS bond length is 2.030 (3) A Ê , which is comparable with those observed in [C 5 H 9 NH(CH 3 )S] 2 CuCl 4 [2.02 (2) A Ê ; Brianso  et al, 1981] The Tab-Tab dications in the crystal of (I) are arranged parallel to each other along the a axis, and the HgI 4 dianions are positioned between the cations.…”

“…In the present case, the formation of the Tab-Tab dication may be due to the oxidation of Tab via oxygen in the presence of Hg 2+ . It was of interest to determine the structure of the title compound, as there are a limited number of documented metal±organic disul®de salts (Brianso  et al, 1981;Casals et al, 1987). Here, we report the crystal structure of the title compound, (I).…”

Bis[4-(dimethylamino)pyridinium] tetrabromidocadmate(II) monohydrate

“…For other tetrahedral ammonium tetrabromidocadmates, see: Altermatt et al (1979); Battaglia et al (1991); Casals et al (1987); Geselle & Fuess (1994); Ishihara et al (1998); Krishnan et al (1991); Sato et al (1986); Waskowska (1994).…”