Polymorphism and piezochromicity in the three-dimensional network-based phosphate RbCuPO₄

Abstract

Rubidium copper phosphate, RbCuPO(4), forms two room-temperature polymorphs that have been investigated with neutron powder diffraction. Polymorph (II) can be converted quantitatively into (I) by grinding the material or by pelletization, and the phase transition is accompanied by a significant colour change from very pale green to sky blue. Polymorph (II) can be obtained essentially free of (I) by quenching from 723 K. Each polymorph shows two unique Cu atoms: in (I) both sites are four-coordinate in a 2:1 ratio, whereas in (II) the atoms are four- and five-coordinate in a 1:1 ratio. In each case these sites are linked by phosphate tetrahedra to form three-dimensional frameworks based on the 4(2)6(3)8-a four-connected net. The Rb atoms are hosted in the six- and eight-ring channels that are similar to those observed in zeolite ABW. The (II) --> (I) phase transition is also accompanied by a volume reduction of 2.1% even though the average coordination of the Cu atoms also falls. The structures of the polymorphs are critically examined and compared with those of KNiPO(4) and KCuPO(4) in terms of hexagonal close packing containing ordered phosphate arrays. As a result of buckling of the six-ring layers, one-dimensional chains of dimerized copper polyhedra are identified in (II), chains that become trimers with mirror symmetry in (I).

Magnetic Properties of the RbMnPO4 Zeolite-ABW-Type Material: A Frustrated Zigzag Spin Chain

“…By inspecting the crystal structures of RbMnPO 4 and RbCoPO 4 , one can notice (see Figure ) that their structures are very similar but correspond to two different configurations. The reported configuration for RbMnPO 4 is the same as the one of the crystal structure of RbZnPO 4 , TlZnPO 4 , and TlZnAsO 4 . , RbCoPO 4 exhibits an opposite configuration like the reported structure of RbCuPO 4 (polymorph II) and KCuPO 4 . ,, The difference between these two crystal structure types is evidenced by the difference in the orientation of the metal and the phosphorus polyhedra within the structure. The positions of phosphorus and metal ions of RbCoPO 4 are inverted with respect to those of RbMnPO 4 (see Figure ).…”

“…Among the ABW-zeotype ABPO 4 materials, several members crystallize in the P 2 1 symmetry. Namely, there are AZnPO 4 (A = Rb, NH 4 ), ,, ACoPO 4 (A = Rb, NH 4 ), KCuPO 4 , RbCuPO 4 (polymorph II), TlMPO 4 (M = Zn, Mg), and TlZnAsO 4 . The crystal structure of RbMnPO 4 was also successfully refined in the space group P 2 1 using the high-resolution powder neutron diffraction data measured on D1A at 10 K. No impurities were detected in the neutron data.…”

“…14,16 RbCoPO 4 exhibits an opposite configuration like the reported structure of RbCuPO 4 (polymorph II) and KCuPO 4 . 4,12,13 The difference between these two crystal structure types is evidenced by the difference in the orientation of the metal and the phosphorus polyhedra within the structure. The positions of phosphorus and metal ions of RbCoPO 4 are inverted with respect to those of RbMnPO 4 (see Figure 3).…”