Polypyrazolylborate analogues without boron: Structural diversity in ligand design and metal complexes

Various pyrazole‐based P,N (2a–c) and N,N (3a–b) ligands have been synthesized. Using representative ligands, NiII, CoII, CuII, and CuI complexes have been prepared and structurally characterized by crystallography. During complexation of CoII and CuII salts, the phosphane part of the P,N ligand oxidized to phosphane oxide. For N,N donor ligands, a dimeric chloro‐bridged NiII complex was obtained. NiII complex 4 is an active catalyst for ethylene oligomerization. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)

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Luminescent α-diimine complexes of ruthenium(II) containing scorpionate ligands

Huang

Seward

Sullivan

et al. 2000

Inorganica Chimica Acta

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Polypyrazolylborate analogues without boron: Structural diversity in ligand design and metal complexes

Abstract: Structural chemistry of organometallic complexes containing pyrazolederived polydentate ligands (without boron) has been reviewed in the context of current results from this laboratory.

Cited by 4 publications

References 70 publications

ChemInform Abstract: Polypyrazolylborate Analogues Without Boron: Structural Diversity in Ligand Design and Metal Complexes

ChemInform Abstract: Polypyrazolylborate Analogues Without Boron: Structural Diversity in Ligand Design and Metal Complexes

Pyrazole‐Tethered Heteroditopic Ligands and Their Transition Metal Complexes: Synthesis, Structure, and Reactivity

Luminescent α-diimine complexes of ruthenium(II) containing scorpionate ligands

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