With the proposal of China’s national “double carbon” strategic goal, carbon capture, utilization and storage (CCUS) technology has attracted more and more attention. Due to the high cost, high energy consumption and high risk of CCUS technology, this technology is still in the initial stage of development in China. Among them, CO2 geological storage is one of the risks, and the environmental monitoring technology of CO2 storage leakage is particularly important in the large-scale popularization and application of CCUS technology in China. On the basis of extensive research on the related literature concerning CO2 storage and leakage, this paper begins with the types and mechanisms of CO2 storage, analyzes the ways and risks of CO2 storage and leakage and then summarizes the existing environmental monitoring technologies of CO2 geological storage and leakage. In the future, China can promote the progress of CO2 geological storage monitoring technology and help achieve the goal of “double carbon” by strengthening the research on CO2 storage mechanism and main control factors, perfecting the risk assessment method of CO2 storage, constructing the monitoring technology system of the CO2 storage life cycle, and standardizing the CO2 storage risk response system.