2020
DOI: 10.26434/chemrxiv.12957314.v1
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Porous Shape-Persistent Rylene Imine Cages with Tunable Optoelectronic Properties and Delayed Fluorescence

Abstract: A simultaneous combination of porosity and tunable optoelectronic properties, common in covalent organic frameworks, are rare in shape-persistent organic cages. Yet, organic cages offer important molecular advantages, the solubility and modularity. Herein, we report the synthesis of a series of chiral imine organic cages with three built-in rylene units by means of dynamic imine chemistry and we investigate their textural and optoelectronic properties. Thereby we demonstrate that the synthesized rylene cages a… Show more

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