2021
DOI: 10.26434/chemrxiv.13507446.v1
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Post-Synthetic ‘Click’ Synthesis of RAFT Polymers with Pendant Self-Immolative Triazoles

Abstract: <div> <div> <div> <p>Self-immolative linkers offer efficient mechanisms for deprotecting ‘caged’ functional groups in response to specific stimuli. Herein we describe a convenient ‘click’ chemistry method for introducing pendant self-immolative linkers to a polymer backbone through post-polymerization modification. The intro duced triazole rings serve both to anchor the stimuli-cleavable trigger groups to the polymer backbone, while also forming a functional part of the self… Show more

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