In this work, binary
and ternary gas mixtures of 1,3,3,3-tetrafluoropropene,
HFO-1234ze(E), and perfluoro-(3-methylbutan-2-one), CF
3
C(
O
)CF(CF
3
)
2
, with CO
2
and synthetic air, are presented as alternatives to SF6 in
medium-voltage electrical equipment. They were used in four medium-voltage
switchgear cubicles replacing SF6 gas, and after a period of time,
under permanent 30 kV AC voltage, gas mixture samples were extracted
and analyzed on the same day using a validated methodology based on
gas chromatography (GC) coupled to mass spectrometry (MS) and thermal
conductivity (TCD). CF
4
(tetrafluoromethane), C
2
F
6
(hexafluoroethane), C
3
F
6
(hexafluoropropylene),
C
3
HF7 (1,1,1,2,2,3,3-heptafluoropropane), CH
2
F
2
(difluoromethane), and the cis and trans-C
3
H
2
F
4
(1,3,3,3-tetrafluoropropene) have been
identified as decomposition products in these gas mixtures. In addition,
a quantity of water has been observed, as well as CO in one of the
cubicles. The most abundant decomposition products identified in gas
mixture samples (C
3
HF
7
and C
3
F
6
) together with water and CO content have been quantified
using commercial gas mixture reference standards. The toxicity and
global warming of the analyzed compounds are evaluated to determine
the most adequate gas mixture among those studied as a candidate to
substitute SF6.