“…The mesopores could allow oxygen to enter the catalytic active sites and promote the transportation of substances, which could improve the ORR activity. 47 As compared with the AC-control, the surface area and pore volume of Fe–Cu–NC- x were slightly reduced, which might be due to the fact that Fe–Cu–NC nanoparticles occupied the partial mesopores of AC.…”
Microbial fuel cell (MFC) is a promising device for converting bioenergy into electrical energy, but its performance is mainly limited by the slow kinetics of oxygen reduction reaction (ORR). Hence,...
“…The mesopores could allow oxygen to enter the catalytic active sites and promote the transportation of substances, which could improve the ORR activity. 47 As compared with the AC-control, the surface area and pore volume of Fe–Cu–NC- x were slightly reduced, which might be due to the fact that Fe–Cu–NC nanoparticles occupied the partial mesopores of AC.…”
Microbial fuel cell (MFC) is a promising device for converting bioenergy into electrical energy, but its performance is mainly limited by the slow kinetics of oxygen reduction reaction (ORR). Hence,...
“…2f). 34 Notably, Fe-N was located at 398.6 AE 0.2 eV, which is very close to the pyrrolic-N, providing evidence for the coordination of Fe atoms with N atoms. 35 The relative contents of pyridinic N species were calculated, and were found to be greatly enhanced on the Fe-N-C@NC surface (55.46%) compared to that on Fe-N-C (42.67%).…”
Porous carbon supported FeNx catalysts have become one of the candidates to replace platinum group metals (PGMs) catalysts towards oxygen reduction reaction (ORR) due to their high intrinsic reactivity and...
“…20e). More importantly, the activity of (Fe,Co)/N-C was significantly higher than that of the single active metal FeNi SAs/NAC catalysts were obtained from the pyrolysis of ZIF-8@FeNi(mIm) x precursor by Bai et al 225 (Fig. 20g).…”
Section: Transition Metals and Transition Metalsmentioning
confidence: 95%
“…FeNi SAs/NAC catalysts were obtained from the pyrolysis of ZIF-8@FeNi(mIm) x precursor by Bai et al 225 (Fig. 20g).…”
Section: Carbon-based Diatomic Metal Catalystsmentioning
The slow oxygen reduction reaction (ORR) kinetics is the main factor restricting the development of fuel cells and metal-air batteries. Carbon-based single-atom catalysts (SACs) have the advantages of high electrical...
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