2006
DOI: 10.1021/jp055916c
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Preparation and Third-Order Optical Nonlinearity of Self-Assembled Chitosan/CdSe−ZnS Core−Shell Quantum Dots Multilayer Films

Abstract: The self-assembled chitosan CdSe quantum dots (QDs) and chitosan CdSe-ZnS core-shell QDs films have been prepared by using layer-by-layer electrostatic technique. The well-ordered nanostructure and the layer-by-layer deposition of the QDs are revealed by AFM and exciton absorption spectra, respectively. The optical nonlinearity of the composite films were studied by using Z-scan technique with femtosecond pulses at the wavelength of 790 nm, the value of third-order susceptibility of core-shell QDs are measured… Show more

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Cited by 109 publications
(59 citation statements)
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“…To demonstrate the enhancement of PL from quantum emitters by silver nanoanteanna rings, a monolayer of CdSe/ZnS semiconductor quantum dots (SQDs) were self-assembled on a quartz glass substrate by electrostatic interactions (see Fig. S2 of the Supporting Information), [53][54][55][56] and then the silver nanorings were dropped onto the separation layer. The excitation laser, with a wavelength 532 nm, illuminated the CdSe/ZnS SQDs from the back side of the substrate with an incidence angle u in ¼ 60 8-82 8 (see Fig.…”
Section: Tunable Photoluminescence Enhancement By Silver Nanoantenna mentioning
confidence: 99%
“…To demonstrate the enhancement of PL from quantum emitters by silver nanoanteanna rings, a monolayer of CdSe/ZnS semiconductor quantum dots (SQDs) were self-assembled on a quartz glass substrate by electrostatic interactions (see Fig. S2 of the Supporting Information), [53][54][55][56] and then the silver nanorings were dropped onto the separation layer. The excitation laser, with a wavelength 532 nm, illuminated the CdSe/ZnS SQDs from the back side of the substrate with an incidence angle u in ¼ 60 8-82 8 (see Fig.…”
Section: Tunable Photoluminescence Enhancement By Silver Nanoantenna mentioning
confidence: 99%
“…Third-order nonlinear optical (NLO) materials with weak nonlinear absorption (NLA) but strong nonlinear refraction (NLR) have attracted considerable attention because of their potential uses in the optical signal processing devices [8][9][10][11][12][13]. The Z-scan method has gained rapid acceptance by the nonlinear optics community as a standard technique for separately determining the nonlinear changes in index and changes in absorption.…”
Section: Introductionmentioning
confidence: 99%
“…Researchers are focusing on semiconductor nanocrystals or quantum dots (QDs) in recent years, [1][2][3][4][5][6][7] due to their unique physical properties and promising potential applications in photonics, solar cells, biotechnology, medicine, and imaging. QDs became more important in the field of nanoscience because of their unique electronic and optical properties such as narrow emission bands, continuous broad absorption band, high quantum yields, and high resistance to photobleaching compared with traditional organic fluorophores.…”
Section: Introductionmentioning
confidence: 99%