Preparation, Determination and Study Toxicity Effects of new Mixed ligands Complexes Derivative from 8- Hydroxy Quinoline with Pd(II)

Kadhium, Afaq Jaber; Abdulmahdi, Bilal Sadiq; Ali, Fatima Jabbar

doi:10.21608/ejchem.2021.73861.3652

Cited by 2 publications

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“…The absence of new band around 526 and 441 cm -1 due to metal nitrogen and oxygen respectively in reagent spectrum and which appearance in complex spectrum. [26][27][28][29][30] Table…”

Section: Infrared Spectrummentioning

confidence: 99%

A Rapid and Sensitive Colorimetric Sequential Injection System for Cu(II) ion Determination Using New Azo Reagent

Khdeeja Jabbar Ali,

Jameelah Lateef Mutasher

2023

J. K. Chem. Sci.

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A sensitive and accurate Sequential Injection Analysis technique for determining Cupper (II) ion in different samples, using a new azo derivative reagent of 8-hydroxy quinoline (HQDABA). The reagent and Cu(II) complex diagnosis included Infrared spectroscopy, Ultraviolet-Visual radiation, Elemental Analysis (CHN), Energy dispersive X-ray spectroscopy (EDX), nuclear magnetic resonance spectroscopy 1HNMR and mass spectroscopy techniques. The method depends on the reaction of Cupper (II) with the (Azo derivative of 8-hydroxy Quinoline) reagent in a neutral medium to form a Brown complex which gave a maximum absorbance at 420 nm. The optimum conditions such as flow rate, Copper (II) volume, reagent volume; pH, reagent concentration, and reaction coil length are thoroughly examined. A Copper (II) curve is constructed, and the suggested method obeys Beer's law over ration range of 1-10 mg/ L. The limits of detection (LOD) and on (LOQ) are determined to be (0.361) mg/ L and(1.204) mg/ L, while Sandell's sensitivity and molar absorption coefficient are to be (0.120) µg/ cm2 and (527.05) L/ mol. cm respectively. The recommended method has given good accuracy with recovery rates ranging from (77.82% - 115% ).

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“…The absence of new band around 526 and 441 cm -1 due to metal nitrogen and oxygen respectively in reagent spectrum and which appearance in complex spectrum. [26][27][28][29][30] Table…”

Section: Infrared Spectrummentioning

confidence: 99%

A Rapid and Sensitive Colorimetric Sequential Injection System for Cu(II) ion Determination Using New Azo Reagent

Khdeeja Jabbar Ali,

Jameelah Lateef Mutasher

2023

J. K. Chem. Sci.

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“…This study focused on the cytotoxic effect of Pd(II) complex on Thyroid cancer cells line (FTC-133) compared with healthy cells line (WRL-68) by taking number of concentrations of Pd(II) complex (6.2-400) µg/ml and adding these concentrations to both cancer and healthy cells by using MTT method [15] , the result is shown that (25)µg/ml of Pd(II) complex is the best concentration to inhibit the tumor of cancer cells . However, it was less influence on healthy cells , which is approved that Pd(II) complex might be used as new medicine of Thyroid cancer line (FTC-133).…”

Section: Cytotoxic Activity Of [Pd(hl) 2 ]mentioning

confidence: 99%

Design, Preparation some transition metal complexes of Chalcone-Azo with Paracetamol ligand and Evaluation anti-biological activity of some complexes

Afaq jabber kadhium,

Mithaq Saeed Mohammed,

Shownm Hasan Baper

2023

J. K. Chem. Sci.

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This search designed new series complexes of (Mn , Fe, Co, Ni, Cu, and Pd)(II) ,which prepared from Chalcone - Azo derived contained Paracetamol . The results illustrate that, the mole ratio (ligand : metal) (2:1) for all complexes and the geometric shapes of complexes were an Octahedral except Pd(II) complex was Square planer. the complexes characterized by ( UV-Visible, FTIR, C.H.N, Electrical molar conductivity and Magnetic susceptibility). This ligand coordinated with metal ions via (N) atom of Azo group and (O) atom of OH group of Paracetamol , the biological examination tested Pd(II)complex as antitumor Thyroid cancer cells(FTC-133) and compered it with healthy cells to evaluate the possibility of using it as therapeutic method. In addition , it tested Cu(II) and Ni(II) complexes as antimicrobial activity towards two types of Gram negative and Gram positive bacteria

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Preparation, Determination and Study Toxicity Effects of new Mixed ligands Complexes Derivative from 8- Hydroxy Quinoline with Pd(II)

Cited by 2 publications

References 0 publications

A Rapid and Sensitive Colorimetric Sequential Injection System for Cu(II) ion Determination Using New Azo Reagent

A Rapid and Sensitive Colorimetric Sequential Injection System for Cu(II) ion Determination Using New Azo Reagent

Design, Preparation some transition metal complexes of Chalcone-Azo with Paracetamol ligand and Evaluation anti-biological activity of some complexes

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