2011
DOI: 10.1016/j.jqsrt.2010.08.016
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Pressure broadening and collisional shift of the Rb D2 absorption line by CH4, C2H6, C3H8, n-C4H10, and He

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Cited by 34 publications
(13 citation statements)
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“…Expected frequency shifts due to collisions between Rb atoms and background gas in the cell can be estimated from previous shift measurements (Rb-Rb collisions 30 and Rb collisions with noble gases 31,32 ). At room temperature the pressure of Rb inside the cell is about 1 × 10 −6 Torr; background gas pressure is also taken to be at this level given that it is unknown.…”
mentioning
confidence: 99%
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“…Expected frequency shifts due to collisions between Rb atoms and background gas in the cell can be estimated from previous shift measurements (Rb-Rb collisions 30 and Rb collisions with noble gases 31,32 ). At room temperature the pressure of Rb inside the cell is about 1 × 10 −6 Torr; background gas pressure is also taken to be at this level given that it is unknown.…”
mentioning
confidence: 99%
“…At these pressures, the expected frequency shifts for both Rb-Rb and Rb-noble gas collisions is < 1 kHz. A higher background pressure (e.g., He in air, about 5 ppmv or 4 mTorr) would still only cause a shift of about 2 kHz 31 .…”
mentioning
confidence: 99%
“…To compare theory with experiment for a compact cell, we used a micro-fabricated 1 × 1 × 1 mm 3 isotopically enriched 87 Rb cell [27]. The isotopic abundance of 85 Rb was found by transmission spectroscopy to be (1.00 ± 0.02)%, in a similar way to that shown in ref. [32].…”
Section: Methodsmentioning
confidence: 60%
“…Experimental and theoretical Faraday-filter spectra on the rubidium D2 line as a function of linear detuning (∆/2π) from the weighted line-centre (384.23042812 THz [76,77]). A 1 mm length vapour cell was used with an isotopic ratio of 99% 87 Rb to 1% 85 Rb. The solid black line in panel (a) shows the experimental filter spectrum and the dashed (red) line shows the fit to theory that includes the natural, self, and buffer gas induced (Γ buf ) Lorentzian broadening effects.…”
Section: Results For Wing and Line-centre Filtersmentioning
confidence: 99%
“…K, Rb and Cs: self broadening of principal series (E) (Vadla et al 2009). Rb: 5s-5p D2 line, broadening by He, CH 4 , C 2 H 6 , C 3 H 8 , n-C 4 H 10 (E) (Zameroski et al 2011). Cs: 6s-6p D2 line, broadening by 3 He, H 2 , HD, D 2 , N 2 , CH 4 , C 2 H 6 , CF 4 (E) (Pitz et al 2010).…”
Section: Broadening By Neutral Atoms and Moleculesmentioning
confidence: 99%