“…Drastic alteration in size and morphology impacts the overall physicochemical and electrochemical properties. Anisotropic growth of crystals demonstrates the exposure of diverse active surfaces ( Gupta et al, 2023 ; Baral et al, 2021 ), alteration in bond energy value, the conception of electron localization/delocalization centres ( Madhu et al, 2023 ), exciton injection via lattice mismatch ( Kundu et al, 2023 ) and alteration in active surface area ( Konar et al, 2023 ) like parameters. Morphology disparity strictly facilitates distortion in atomic arrangement and steric constraints, thus impacting the overall chemo-absorption course ( Wu et al, 2021 ).…”