Progress in organic reactions catalyzed by bimetallic nanomaterials

Cai, Shuangfei; Wang, Dingsheng; Niu, Zhiqiang; Li, Yadong

doi:10.1016/s1872-2067(12)60701-3

Cited by 42 publications

(11 citation statements)

References 122 publications

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“…A review by Cai et al [34] provides a summary of bimetallic nanomaterial-catalysed organic transformations and expresses the potential for such bimetallic nanoparticle catalysis to have significant reaction scope, especially with palladium such as magnetically separable "quasi-homogeneous" Pd-Ni nanoalloys, Au-Pd particles confined in silica nanorattles, carbon-supported bimetallic Pd-M (M = Ag, Ni, and Cu) nanoparticles, etc. It was observed that the carbon-supported bimetallic nanoparticles Pd-Cu/C prepared by γ-irradiation at room temperature exhibits high catalytic efficiency in the Suzukiand Heck-type coupling reactions.…”

Section: Nano Catalysismentioning

confidence: 99%

Heck Reaction—State of the Art

Jagtap¹

2017

Catalysts

182

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Abstract:The Heck reaction is one of the most studied coupling reactions and is recognized with the Nobel Prize in Chemistry. Thousands of articles, hundreds of reviews and a number of books have been published on this topic. All reviews are written exhaustively describing the various aspects of Heck reaction and refer to the work done hitherto. Looking at the quantum of the monographs published, and the reviews based on them, we found a necessity to summarize all reviews on Heck reaction about catalysts, ligands, suggested mechanisms, conditions, methodologies and the compounds formed via Heck reaction in one review and generate a resource of information. One can find almost all the catalysts used so far for Heck reaction in this review.

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Section: Nano Catalysismentioning

confidence: 99%

Heck Reaction—State of the Art

Jagtap¹

2017

Catalysts

182

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“…506,507 Unfortunately, very few reviews are devoted to the application of bimetallic catalysts and bimetallic nanoparticles in organic synthesis. These issues are covered most comprehensively in reviews by Cai et al 508 and by Yu et al…”

Section: Bimetallic Catalysts In Organic Synthesismentioning

confidence: 99%

Development of new methods in modern selective organic synthesis: preparation of functionalized molecules with atomic precision

Ananikov¹,

Khemchyan²,

Іvanova³

et al. 2014

Russ. Chem. Rev.

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“…Muradova et al have used iron–copper (Fe‐Cu) bimetallic nanoparticles for the removal of nitrate from water . Wang et al have synthesized cobalt–palladium bimetallic nanoparticles as a catalyst for hydrogenation, selective oxidation, and hydrogenolytic and coupling reactions . Ataee‐Esfahani et al have used gold–platinum nanoparticles as an electrocatalyst for methanol oxidation .…”

Section: Introductionmentioning

confidence: 99%

Investigation of role of urea in morphologically controlled synthesis of calcium‐bismuth bimetallic nanoparticles from chicken egg shells and its catalytic and fuel additive applications

Khan

Jamil

Zahid

et al. 2019

J Chinese Chemical Soc

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A comparative study on the role of urea in controlling the morphology of calcium‐bismuth (Ca5Bi3) bimetallic nanoparticles is carried out. Calcium‐bismuth bimetallic nanoparticles are synthesized in the presence and absence of urea using the solvothermal method. The morphology of the synthesized products is analyzed by scanning electron microscopy. The composition of the product is analyzed by energy‐dispersive X‐ray spectroscopic and X‐ray diffraction (XRD) analyses. Reitveld refinements are performed on the XRD data, and lattice parameters are optimized. Reitveld‐refined parameters are used to construct the structural model of the calcium‐bismuth product. The formation mechanism of needle like particles from an orthorhombic unit cell is also proposed. The degradation of Congo red dye is catalyzed by synthesized Ca5Bi3 bimetallic nanoneedles in an aqueous medium. The effect of catalyst dose on the apparent rate constant (kapp) of degradation is studied and compared with literature. Ca5Bi3 bimetallic nanoneedles are also used as an additive in commercial diesel obtained from Pakistan State Oil, Limited. The effect of an additive dose on the calorific value of diesel is studied. How the Ca5Bi3 additive influenced other fuel quality parameters such as flash point, fire point, pour point, cloud point, kinematic viscosity, and specific gravity is also studied.

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Progress in organic reactions catalyzed by bimetallic nanomaterials

Cited by 42 publications

References 122 publications

Heck Reaction—State of the Art

Heck Reaction—State of the Art

Development of new methods in modern selective organic synthesis: preparation of functionalized molecules with atomic precision

Investigation of role of urea in morphologically controlled synthesis of calcium‐bismuth bimetallic nanoparticles from chicken egg shells and its catalytic and fuel additive applications

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