Prolonged Red Persistent Luminescence in Bi³⁺ Single-Doped LiGa₅O₈: Regulating Traps by Site Selective Occupation

Abstract

Persistent luminescence (PersL) materials with impressive superiorities in optical performance have shown tremendous potential for information encryption application. Herein, a Bi 3+ -doped LiGa 5 O 8 PersL material is facilely synthesized by a simple solid-state reaction. Site selective and preferential occupation of Bi 3+ ions at distinct Ga 3+ and Li + polyhedra sites in LiGa 5 O 8 endows it with a bimodal emission at 511 and 718 nm upon UV excitation at 254 nm. After removing the light source, an intense red afterglow was observed due to the generation of more and deeper traps classified as the oxygen vacancy defect (V O•• ) and the impurity defect (Bi Li ••). It is rarely reported in inorganic phosphors to achieve the Bi 3+ single doping-activated red PersL. The LiGa 5 O 8 :x% Bi 3+ (with x = 0.5−5.0) samples also exhibit tunable PL and timedependent PersL properties. Combined with the Morse Code, a multiple information encryption model based on the abnormal optical properties of LiGa 5 O 8 :x% Bi 3+ (x = 0, 0.5, and 5.0) samples was designed for high-level dynamic anticounterfeiting. These achievements further validate the use of the Bi 3+ single doping strategy to explore excellent PersL materials and expand their multifunctional optical applications.