Prospective hazard and toxicity screening of sodium-ion battery cathode materials

Baumann, Manuel; Peters, Jens F.; Häringer, Marcel; Schmidt, Marius; Schneider, Luca; Bauer, Werner; Binder, Joachim R.; Weil, Marcel

doi:10.1039/d3gc05098j

Green Chem.

2024

DOI: 10.1039/d3gc05098j

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Prospective hazard and toxicity screening of sodium-ion battery cathode materials

Manuel Baumann,

Jens F. Peters,

Marcel Häringer

et al.

Abstract: Sodium-ion batteries (SiB) are considered as a serious alternative to current Lithium-ion batteries (LiBs). However, SiB are an emerging technology in an early stage of development with a wide set...

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Cited by 2 publications

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Natural Low‐Melting Mixture Solvents for Green Recovery of Spent All‐Solid‐State Sodium‐Ion Batteries with Superior Efficiency over Lithium‐Ion Batteries

Chen,

Shen,

Liu

et al. 2024

ChemSusChem

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Spent all‐solid‐state sodium‐ion batteries (ASIBs) containing toxic and precious metal would be produced significantly and lead to resource waste and environmental pollution as the wide application of ASIBs in the near future. Therefore, it is necessary to develop green strategy for recovery of ASIBs. Here, we propose a safe, mild and green strategy to recover toxic and precious metals from cathode/solid electrolyte of ASIBs by using natural low‐melting mixture solvents (LoMMSs) with high selectivity and high leaching efficiency. Natural LoMMSs are abundant, natural available, cheap, non‐flammable, biodegradable and biocompatible. Results show that natural LoMMSs could leach nearly 100% Na and achieve superhigh Na/Zr selectivity of up to 58 from ASIBs at mild temperature, outperforming the recycling efficiency and selectivity of lithium‐ion batteries cathode. More importantly, we find that water could be used as a green and low‐cost anti‐solvent to precipitate the extracted metal from the leachate with low‐energy consumption at room temperature. This work provides a cost‐effective, energy‐saving, mild, green strategy for the recovery of cathode/solid electrolyte from spent ASIBs with high safety and high selectivity.

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Natural Low‐Melting Mixture Solvents for Green Recovery of Spent All‐Solid‐State Sodium‐Ion Batteries with Superior Efficiency over Lithium‐Ion Batteries

Chen,

Shen,

Liu

et al. 2024

ChemSusChem

View full text Add to dashboard Cite

show abstract

Na3V2(PO4)3 derived cathode materials for sodium-ion batteries (SIBs): A review

Banerjee,

Choudhary,

Ansari

2024

Future Batteries

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Prospective hazard and toxicity screening of sodium-ion battery cathode materials

Abstract: Sodium-ion batteries (SiB) are considered as a serious alternative to current Lithium-ion batteries (LiBs). However, SiB are an emerging technology in an early stage of development with a wide set...

Cited by 2 publications

References 60 publications

Natural Low‐Melting Mixture Solvents for Green Recovery of Spent All‐Solid‐State Sodium‐Ion Batteries with Superior Efficiency over Lithium‐Ion Batteries

Natural Low‐Melting Mixture Solvents for Green Recovery of Spent All‐Solid‐State Sodium‐Ion Batteries with Superior Efficiency over Lithium‐Ion Batteries

Na3V2(PO4)3 derived cathode materials for sodium-ion batteries (SIBs): A review

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