Pt(II) diimine complexes bearing difluoro-boron-dipyrromethene acetylide ligands: Synthesis, photophysics, aggregation included emission and optical power limiting properties

Li, Rui; Zhu, Senqiang; Lu, Jiapeng; Hong, Shiming; Zhu, Hongjun

doi:10.1016/j.dyepig.2017.08.024

Cited by 30 publications

(24 citation statements)

References 42 publications

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“…Laser is one of the indispensable elements in the NLO domains, [189,190] and the sustainable, jarless, and adjustable laser resources are the fundamentals of yielding and characterizing the diverse NLO effects. [191] For the moment, the solid-SSLs recline principally on the inorganic materials, such as TMDs, [192] perovskites, [193] MXene.…”

Section: Organic Sslmentioning

confidence: 99%

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Aggregation‐induced emission materials for nonlinear optics

Han

et al. 2021

Aggregate

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Aggregation‐induced emission (AIE) is a vital photophysical phenomenon that the luminogens in the concentrated or aggregated cases will engender the dramatically boosted emission in comparison with the dispersive states. Given this extraordinary emitting capacity exactly resolves the aggregation‐caused quenching (ACQ) situations residing in the traditional luminophores, the booming AIE luminogens have drawn tremendous interest owing to their advanced performances and colossal potential applications in various areas. Further exploitations of AIE molecules also drive the research interests in the midst of these AIE materials toward the nonlinear optical (NLO) regime. The combination of AIE and NLO effects have nurtured some unforeseen properties of AIE materials and extended their application spheres. Therefore, some NLO‐active AIE materials have been wielded in many crucial applications, for example, optical limiting, laser, bioimaging, and photodynamic therapy. Meanwhile, the impacts of aggregate on the NLO effect also deserve deep considerations and pursuits, and the modifications of aggregates promise an easy, efficient, and prompt avenue to tune the NLO properties of materials. The recent achievements and progress in the NLO properties of AIE materials have been summarized in this review. The second‐order and third‐order NLOs of the AIE materials have been introduced and their correlative applications have been discussed.

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Section: Organic Sslmentioning

confidence: 99%

“…[ 187 ] (E and F) Reproduced with permission: Copyright 2017, Elsevier. [ 188 ] (G) Reproduced with permission: Copyright 2019, American Chemical Society. [ 201 ] (H and I) Reproduced with permission: Copyright 2019, WILEY‐VCH.…”

Section: Nlo Applications Of Aie Materialsmentioning

confidence: 99%

Aggregation‐induced emission materials for nonlinear optics

Han

et al. 2021

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“…To minimize their impact on sensitive human eyes and optical devices, optical‐limiting (OL) materials with high transmission and decreasing transmission of progressively increasing light intensities have received considerable attention [3] . Typical OL materials contain carbon‐based materials (including carbon black, carbon nanotubes, fullerenes and graphene), [4] organic dyes and polymers (such as phthalocyanine and porphyrin), [5, 6] inorganic metal nanoparticle and quantum dots, [7–9] as well as organic and inorganic hybrid materials [10–16] . Hybrid materials possessing flexibility and possible synergic eﬀects of diverse components are promising OL materials.…”

Section: Introductionmentioning

confidence: 99%

“…[3] Typical OL materials contain carbon-based materials (including carbon black, carbon nanotubes, fullerenes and graphene), [4] organic dyes and polymers (such as phthalocyanine and porphyrin), [5,6] inorganic metal nanoparticle and quantum dots, [7][8][9] as well as organic and inorganic hybrid materials. [10][11][12][13][14][15][16] Hybrid materials possessing flexibility and possible synergic effects of diverse compo-nents are promising OL materials. As a result, aggregated crystalline materials like coordination polymers, metalorganic frameworks and metal complexes are among the materials that might become the next generation in the current field.…”

Section: Introductionmentioning

confidence: 99%

“…As a result, aggregated crystalline materials like coordination polymers, metalorganic frameworks and metal complexes are among the materials that might become the next generation in the current field. [12][13][14][15][16] A noteworthy reason is that the variation of metal ions and ligands may offer more opportunities for fine-tuning of the optical properties. Metal molecular rings of high nuclearity have long fascinated chemists due to their aesthetically pleasing structures and interesting properties.…”

Section: Introductionmentioning

confidence: 99%

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Record Aluminum Molecular Rings for Optical Limiting and Nonlinear Optics

Zheng

Wang

et al. 2022

Angewandte Chemie

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Crystalline cluster materials, a class of functional motif aggregations, provide a great opportunity for tuning the properties stemming from the flexible and accurate variation of inorganic and organic compositions. In this study, we demonstrate the effects of functional ligand and ring size regulation on the structures and third‐order nonlinear optical (NLO) properties. Revealed by the single‐crystal X‐ray analysis results, aluminum molecular ring expansion is achieved by 2×9 and 3×6 strategies. In terms of the given organic shells, we further tuned the aluminum molecular ring sizes from 3.0 nm to 1.7 nm. The picosecond Z‐scan measurements results revealed that the third‐order NLO performances do not only depend on the general conjugate interactions but are also related to hydrogen bonding, polarizability, and ring sizes. The large nonlinear absorption coefficient and onset prove that the observed samples are promising candidates for the field of nonlinear optics.

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AIE‐active BODIPY Derivatives

Liu

Huang

et al. 2022

Handbook of Aggregation‐Induced Emission

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Pt(II) diimine complexes bearing difluoro-boron-dipyrromethene acetylide ligands: Synthesis, photophysics, aggregation included emission and optical power limiting properties

Cited by 30 publications

References 42 publications

Aggregation‐induced emission materials for nonlinear optics

Aggregation‐induced emission materials for nonlinear optics

Record Aluminum Molecular Rings for Optical Limiting and Nonlinear Optics

AIE‐active BODIPY Derivatives

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