1992
DOI: 10.1016/0009-2614(92)80844-2
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Pulse radiolytic generation and photolysis of diphenyldiazomethane radical anion (Ph2CN2−.)

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“…The strong wavelength dependence of the photodestruction quantum yields of diazo compounds is consistent with excited-state deactivation pathways other than N 2 loss. In addition, the broad absorption band of the short-time feature, which extends from 320 to beyond 500 nm (squares in Figure ), resembles the spectrum of Ph 2 CN 2 •- reported by Chateauneuf. , Excited-state absorption by singlet states of aromatic compounds frequently resembles that of the corresponding radical anions due to their similar electronic configurations.…”
Section: Discussionsupporting
confidence: 66%
“…The strong wavelength dependence of the photodestruction quantum yields of diazo compounds is consistent with excited-state deactivation pathways other than N 2 loss. In addition, the broad absorption band of the short-time feature, which extends from 320 to beyond 500 nm (squares in Figure ), resembles the spectrum of Ph 2 CN 2 •- reported by Chateauneuf. , Excited-state absorption by singlet states of aromatic compounds frequently resembles that of the corresponding radical anions due to their similar electronic configurations.…”
Section: Discussionsupporting
confidence: 66%