Qualitative and quantitative electrochemical studies of multivalent elements in molten oxide glasses

Tilquin, Jy.; Glibert, Jacques; Claes, P.

doi:10.1016/0013-4686(93)85002-g

Cited by 22 publications

(2 citation statements)

References 47 publications

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“…A comparison between SWV and DPV for both, reversible and irreversible systems, shows that, under analogous experimental conditions, the peak currents obtained by SWV are about 2-4 times higher than those obtained by DPV [4]. In addition, it is easier to implement and less time consuming [5].…”

Section: Introductionmentioning

confidence: 96%

Square Wave Voltammetry for Selective Detection of Dopamine Using Polyglycine Modified Carbon Ionic Liquid Electrode

Liu

Wei

2011

Electroanalysis

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The electrochemical polymerization of glycine on carbon ionic liquid electrode (CILE) was described. The presence of ionic liquid on the surface of CILE facilitated the electropolymerization of glycine. The polyglycine modified CILE provided a valid and simple approach to selectively detect dopamine in the presence of AA in physiological environment. The proposed sensor not only decreased the voltammetric responses of AA but also dramatically enhanced the oxidation peak current of DA compared to bare CILE. Using square wave voltammetry, the modified CILE showed good electrochemical behavior to DA, a linear range of 1.0 10 À7 -3.0 10 À4 M in the presence of 1 mM ascorbic acid (AA) and a detection limit of 5.0 10 À9 M was estimated (S/N = 3).

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Section: Introductionmentioning

confidence: 96%

Square Wave Voltammetry for Selective Detection of Dopamine Using Polyglycine Modified Carbon Ionic Liquid Electrode

Liu

Wei

2011

Electroanalysis

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“…Owing to the exceptional characteristics and fast scan rate together with high sensitivity and robust analysis, square wave voltammetry is favored over other available analytical methods for the sensitive detection of DA. [10] Studies are being executed to establish a novel methodology for sensitive detection of DA via chemically modified electrodes which confer good sensitivity, excellent selectivity, reproducibility, and stability. [11] In present investigation, we modified glassy carbon electrode (GCE) by the electrochemical reduction of 4-carboxyphenyldiazonium generated from the reaction of 4-aminobenzoic acid with nitrous acid to make phenyl carboxylic acid-modified GCE (PC-GCE).…”

Section: Introductionmentioning

confidence: 99%

Electrochemical Detection of Dopamine using a Phenyl Carboxylic Acid‐Functionalized Electrode Made by Electrochemical Reduction of a Diazonium Salt

et al. 2022

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A glassy carbon electrode (GCE) has been modified by an in situ electrochemical reduction of an aryldiazonium salt generated from the reaction of 4‐aminobenzoic acid and sodium nitrite in acidic ethanolic solution. The as‐prepared phenyl carboxylic acid‐modified glassy carbon electrode has been, for the first time, used for the electrochemical determination of dopamine. Under optimal experimental parameters, outstanding electrocatalytic activity, high sensitivity at a LOD of 5.6×10 −9 m , and broad linearity of 0.1 to 1000 μ m were obtained. The crafted electrochemical platform demonstrated excellent stability, specificity, and anti‐interference capability towards the sensing of dopamine.

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In situ electrochemical and spectrophotometric investigation of the oxygen pressure dependence of the [Cr(VI)]/[Cr(III)] ratio in a borosilicate melt

Claes

Duveiller

Tilquin

et al. 1996

Ber Bunsenges Phys Chem

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The ratio R = [Cr(VI)]/[Cr(III)] has been measured in a Na,0~1.2Si0,~1.2B20, melt at 1000°C by spectrophotometry and by electrochemistry as a function of the partial pressure of oxygen in the gaseous atmosphere above the melt. Spectrochemical and electrochemical determinations are in quite good agreement and fit the linear relationship between log R and log P(Oz) which is predicted by a thermodynamic development. This double agreement gives a good degree of confidence to in situ high temperature electrochemical measurements in oxide melts.

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Qualitative and quantitative electrochemical studies of multivalent elements in molten oxide glasses

Cited by 22 publications

References 47 publications

Square Wave Voltammetry for Selective Detection of Dopamine Using Polyglycine Modified Carbon Ionic Liquid Electrode

Square Wave Voltammetry for Selective Detection of Dopamine Using Polyglycine Modified Carbon Ionic Liquid Electrode

Electrochemical Detection of Dopamine using a Phenyl Carboxylic Acid‐Functionalized Electrode Made by Electrochemical Reduction of a Diazonium Salt

In situ electrochemical and spectrophotometric investigation of the oxygen pressure dependence of the [Cr(VI)]/[Cr(III)] ratio in a borosilicate melt

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