Quantifying low-energy ICP-MS isotope deposition

Liezers, Martin; Dion, Michael P.; Eiden, Gregory C.; Thomas, May-Lin P.

doi:10.1039/c8ja00447a

Cited by 2 publications

(2 citation statements)

References 15 publications

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“…119 Novel applications of ICP-MS instruments to manufacture enriched isotopes must be mentioned as a future trend, where the electron multiplier is substituted by a metal foil to collect the enriched isotopes in ng to mg quantities. 135,136…”

Section: Discussionmentioning

confidence: 99%

Isotopic measurements using ICP-MS: a tutorial review

Penanes

Reguera-Galan

Huelga-Suarez

et al. 2022

J. Anal. At. Spectrom.

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Section: Discussionmentioning

confidence: 99%

Isotopic measurements using ICP-MS: a tutorial review

Penanes

Reguera-Galan

Huelga-Suarez

et al. 2022

J. Anal. At. Spectrom.

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“…(13) Isotopic separation is, however, not a trivial task as their physico-chemical properties are almost identical. Isotope separation have been demonstrated by several techniques including molecular sieving, (14) mass spectrometry, (15) laser ionization, (7,16) cryogenic distillation processes, (17) thermal cycling absorption process (TCAP) (18) among others. Many of these approaches are inefficient, can be applied to only a limited number of isotopes, and require expensive technologies that are costly and maintenance intensive.…”

Section: Introductionmentioning

confidence: 99%

Controlled Release of Hydrogen Isotopes from Hydride-Magnetic Nanomaterials

Murph

Coopersmith

Sessions

et al. 2020

ACS Appl. Mater. Interfaces

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In this work, hydrogen isotopes in the form of protium and deuterium were rapidly desorbed from magnetic-hydride iron oxide-palladium (Fe2O3-Pd) hybrid nanomaterials using an alternating magnetic field (AMF). Palladium, a hydride material with a well-known hydrogen isotope effect, was deposited on Fe2O3 magnetic nanoparticle support by solution chemistries and used as a hydrogen isotope storage component. The morphological, structural, optical, and magnetic studies reveal that the Fe2O3-Pd nanoparticles (NPs) are hybrid structures exhibiting both hydrogen isotope storage (Pd) and magnetic (Fe2O3) properties. The hydrogen isotope sorption/desorption behavior of metal hydride-magnetic nanomaterials was assessed by isothermal pressure-composition response curves (isotherms). The amount and rate of hydrogen isotope gas release was tuned by simply adjusting the strength of the magnetic field strength applied. Protium and deuterium displayed a similar loading capacity, namely H/M 0.55 and H/M=0.45, but different plateau pressures. Significant differences in the kinetics of release for protium and deuterium during magnetic heating were observed. A series of magnetically induced charge-discharge cycling experiments were conducted showing that this is a highly reproducible and robust process.

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Quantifying low-energy ICP-MS isotope deposition

Abstract: Mass spectrometry (MS) offers an alternative approach to chemical or chromatographic separations to selectively isolate and collect individual isotopes of an element for analytical purposes.

Cited by 2 publications

References 15 publications

Isotopic measurements using ICP-MS: a tutorial review

Isotopic measurements using ICP-MS: a tutorial review

Controlled Release of Hydrogen Isotopes from Hydride-Magnetic Nanomaterials

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