Quantifying the Ground‐State Hydrogen‐Bond Formation of a Super‐Photoacid by Inspecting Its Excited‐State Dynamics
Ye‐Jin Choi,
Hak‐Won Nho,
Ye‐Jin Kim
et al.
Abstract:The identification and quantification of hydrogen (H)‐bonded complexes form the cornerstone of reaction‐mechanism analysis in ultrafast proton transfers. Traditionally, the Benesi‐Hildebrand method has been employed to obtain the formation constants of H‐bonded complexes, given that H‐bonding additives induce an alteration in spectral features exclusively through H‐bond formation. However, if the additive introduction impacts the bulk polarity of the solution, inducing a spectral shift, the spectroscopic metho… Show more
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