Quantum effects for electron-transfer reactions in the "inverted region"

Electrochemiluminescence of Organometallics and Other Transition Metal Complexes

“…At a terminal ac voltage of 4 V and a frequency of 30 Hz we observed a weak eel which was clearly identified as the IL emission of Pt(QO) 2 .…”

“…The potential difference between Pt(QO) 2 and Pt(QO) ~ is 2.6 V. This is certainly sufficient to populate the emitting IL state which lies around 2.0 V above the ground state.…”

“…= -2.33 (55) participates in the electrolysis and generation of excited [Cu(py)l] 4 -Pt(8-quinolinolate) 2 The excited states which are responsible for the eel of the previous examples are of the CTML type or involved in metal-metal bonding of polynuclear complexes.…”

“…The subsequent annihilation leads to the formation of electronically excited Pt(QO) 2 The low eel intensity may be associated with the observation that the electrochemical oxidation and reduction of Pt(QO) 2 is largely irreversible.…”

Structural properties and electron transfer reactivity of NX3/NX3+ (X=H, F) coupling systems

“…In the last two decades, electron transfer (ET) reactions have continued to be the subject of many theoretical [1][2][3] and experimental [4][5][6] studies either in chemistry or biology. In general, ET can occur in a certain range of contact distance.…”