“…[24][25][26] The first examples with anionic aryloxo-functionalized NHCs, were reported by Shen et al 27,28 Lavoie and co-workers reported the complexes with neutral imine-functionalized NHCs. 29,30 The group of Hahn and Chen reported the octahedral complexes with pyridinyl 31 and pyrimidinyl 32,33 substituted NHC respectively. Herein, we report the syntheses and structures of a series of iron complexes of a bidentate picolyl-NHC ligand, along with their reactivity including the interconversions, transmetalation, C-C bond formations, and ligand deprotonation accompanied by the dearomatization of the pyridine moiety.…”